Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
A Stable Hexaazaoctacene Cruciform σ‐Dimer
Buchwald‐Hartwig coupling of a triisopropylsilyl (TIPS)‐ethynylated dibromo‐N,N'‐dihydrotetraazapentacene with 1,4‐bis(TIPS‐ethynyl)‐2,3‐diaminonaphthalene furnishes a dihydrohexaazaoctacene. Its oxidation with MnO2 results in a 7,7'‐bi(hexaazaoctacenyl). In addition to eight TIPS‐ethynyl groups, the bioctacene motif protects the azaoctacene subunits. The biazaoctacenyl displays a τ1/2 of > 5 d in dilute solution under ambient conditions. In the crystalline state it is persistent for > 10 months.
A Stable Hexaazaoctacene Cruciform σ‐Dimer
Buchwald‐Hartwig coupling of a triisopropylsilyl (TIPS)‐ethynylated dibromo‐N,N'‐dihydrotetraazapentacene with 1,4‐bis(TIPS‐ethynyl)‐2,3‐diaminonaphthalene furnishes a dihydrohexaazaoctacene. Its oxidation with MnO2 results in a 7,7'‐bi(hexaazaoctacenyl). In addition to eight TIPS‐ethynyl groups, the bioctacene motif protects the azaoctacene subunits. The biazaoctacenyl displays a τ1/2 of > 5 d in dilute solution under ambient conditions. In the crystalline state it is persistent for > 10 months.
A Stable Hexaazaoctacene Cruciform σ‐Dimer
Maier, Steffen (Autor:in) / Jester, Fabian (Autor:in) / Hoffmann, Marvin T. (Autor:in) / Rominger, Frank (Autor:in) / Freudenberg, Jan (Autor:in) / Dreuw, Andreas (Autor:in) / Bunz, Uwe H. F. (Autor:in)
Advanced Science ; 9
01.09.2022
6 pages
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
acenes , azaoctacene , biacenyl , heteroacene , octacene , stabilization
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