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Comparison of Trace Organic Chemical Removal Efficiencies between Aerobic and Anaerobic Membrane Bioreactors Treating Municipal Wastewater
Evaluating persistent trace organic chemicals (TOrCs) and transformation products (TPs) in membrane bioreactors (MBRs) is essential, given that MBRs are now widely implemented for wastewater treatment and water reuse. This research applied comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry (GC×GC/TOF-MS)-based nontargeted analysis to compare the effectiveness of parallel aerobic and anaerobic MBRs (AeMBRs and AnMBRs, respectively), treating the same municipal wastewater. The average total chromatographic feature peak area abundances were significantly reduced by 84% and 72% from influent to membrane permeate in both the AeMBR and AnMBR (p < 0.05), respectively. However, the reduction of the average number of chromatographic features was significant for only AeMBR treatment (p = 0.006). A similar number of TPs were generated during both AeMBR and AnMBR treatments (165 vs 171 compounds, respectively). The overall results suggest that the AeMBR was more effective for reducing the diversity of TOrCs than the AnMBR, but both aerobic and anaerobic processes had a similar reduction of TOrC abundance. Suspect screening analysis using GC×GC/TOF-MS, which resulted in the tentative identification of 351 TOrCs, proved to be a powerful approach for uncovering compounds previously unreported in wastewater, including many fragrances and personal care products.
This study compares the persistence, removal, and transformation of organic chemicals in parallel aerobic and anaerobic membrane bioreactor systems treating municipal wastewater using a nontargeted analysis based on GC×GC/TOF-MS.
Comparison of Trace Organic Chemical Removal Efficiencies between Aerobic and Anaerobic Membrane Bioreactors Treating Municipal Wastewater
Evaluating persistent trace organic chemicals (TOrCs) and transformation products (TPs) in membrane bioreactors (MBRs) is essential, given that MBRs are now widely implemented for wastewater treatment and water reuse. This research applied comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry (GC×GC/TOF-MS)-based nontargeted analysis to compare the effectiveness of parallel aerobic and anaerobic MBRs (AeMBRs and AnMBRs, respectively), treating the same municipal wastewater. The average total chromatographic feature peak area abundances were significantly reduced by 84% and 72% from influent to membrane permeate in both the AeMBR and AnMBR (p < 0.05), respectively. However, the reduction of the average number of chromatographic features was significant for only AeMBR treatment (p = 0.006). A similar number of TPs were generated during both AeMBR and AnMBR treatments (165 vs 171 compounds, respectively). The overall results suggest that the AeMBR was more effective for reducing the diversity of TOrCs than the AnMBR, but both aerobic and anaerobic processes had a similar reduction of TOrC abundance. Suspect screening analysis using GC×GC/TOF-MS, which resulted in the tentative identification of 351 TOrCs, proved to be a powerful approach for uncovering compounds previously unreported in wastewater, including many fragrances and personal care products.
This study compares the persistence, removal, and transformation of organic chemicals in parallel aerobic and anaerobic membrane bioreactor systems treating municipal wastewater using a nontargeted analysis based on GC×GC/TOF-MS.
Comparison of Trace Organic Chemical Removal Efficiencies between Aerobic and Anaerobic Membrane Bioreactors Treating Municipal Wastewater
Johnson, Jade L. (author) / Dodder, Nathan G. (author) / Mladenov, Natalie (author) / Steinberg, Lauren (author) / Richardot, William H. (author) / Hoh, Eunha (author)
ACS ES&T Water ; 4 ; 1381-1392
2024-04-12
Article (Journal)
Electronic Resource
English
Performance Evaluation of Anaerobic Bioreactors in Treating Swine Wastewater
British Library Online Contents | 2000
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