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Effects of surfactants and adhesion promoters on the bitumen-minerals interfacial bond during breaking of bitumen emulsions
Cold mix asphalt (CMA) emulsion technology has been the subject of research for many decades due to its proven environmental and economic benefits. However, issues relating to its mechanical performance still need to be investigated in order to understand the breaking mechanisms of bitumen emulsions and the surface chemistry involved. Bitumen emulsions are designed to break in a controlled manner to achieve the required level of performance for producing good quality cold asphalt mixtures. In this work, experiments on the coalescence of two bitumen droplets were carried out on a selected grade of Nynas bitumen. In an emulsion environment, the cohesion between bitumen droplets as well as their adhesion to a mineral surface was investigated. The cohesion and adhesion properties were analyzed by varying selected surfactant types and adhesion promoters in the water phase. The research showed that the presence of emulsifiers (with concentrations above the critical micelle concentration) in the water phase inhibits the adhesion of bitumen droplets to the mineral surface. However, a very small addition (0.02%) of adhesion promoter reverses the situation completely, and adhesion is dominant rather than cohesion. Moreover, the kinetics of the coalescence process is strongly controlled by the water phase temperature. ; QC 20180221
Effects of surfactants and adhesion promoters on the bitumen-minerals interfacial bond during breaking of bitumen emulsions
Cold mix asphalt (CMA) emulsion technology has been the subject of research for many decades due to its proven environmental and economic benefits. However, issues relating to its mechanical performance still need to be investigated in order to understand the breaking mechanisms of bitumen emulsions and the surface chemistry involved. Bitumen emulsions are designed to break in a controlled manner to achieve the required level of performance for producing good quality cold asphalt mixtures. In this work, experiments on the coalescence of two bitumen droplets were carried out on a selected grade of Nynas bitumen. In an emulsion environment, the cohesion between bitumen droplets as well as their adhesion to a mineral surface was investigated. The cohesion and adhesion properties were analyzed by varying selected surfactant types and adhesion promoters in the water phase. The research showed that the presence of emulsifiers (with concentrations above the critical micelle concentration) in the water phase inhibits the adhesion of bitumen droplets to the mineral surface. However, a very small addition (0.02%) of adhesion promoter reverses the situation completely, and adhesion is dominant rather than cohesion. Moreover, the kinetics of the coalescence process is strongly controlled by the water phase temperature. ; QC 20180221
Effects of surfactants and adhesion promoters on the bitumen-minerals interfacial bond during breaking of bitumen emulsions
Khan, Abdullah (author) / Redelius, Per (author) / Kringos, Nicole (author)
Article (Journal)
Electronic Resource
English
Breaking Control of Bitumen Emulsions
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