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Post-Li batteries: promises and challenges
Current societal challenges in terms of energy storage have prompted an intensification in the research aiming at unravelling new high energy density battery technologies. These would have the potential of having disruptive effects in the world transition towards a less carbon-dependent energy economy through transport, both by electrification and renewable energy integration. Aside from controversial debates on lithium supply, the development of new sustainable battery chemistries based on abundant elements is appealing, especially for large-scale stationary applications. Interesting alternatives are to use sodium, magnesium or calcium instead of lithium. While for the Na-ion case, fast progresses are expected as a result of chemical similarities with lithium and the cumulated Li-ion battery know-how over the years, for Ca and Mg the situation is radically different. On the one hand, the possibility to use Ca or Mg metal anodes would bring a breakthrough in terms of energy density; on the other, development of suitable electrolytes and cathodes with efficient multivalent ion migration are bottlenecks to overcome. ; Funding from the European Union’s Horizon 2020 research and innovation programme is acknowledged, both from the European Research Council (A. Ponrouch ERC-2016-STG, CAMBAT grant agreement no. 715087) and FETOPEN-1-2016-2017 (CARBAT, grant agreement no. 766617). Acknowledgements. Authors acknowledge ALISTORE-ERI members and NAIADES (H2020, 646433) partners for helpful discussions and are grateful to Fanny Barde (Toyota Motor Europe) and M. Elena Arroyo-de Dompablo for fruitful collaboration. Authors are grateful to Ministry of Science, Innovation and Universities for support through MAT2017-86616-R and ‘Severo Ochoa’ Programme for Centres of Excellence in R&D (SEV-2015-0496). ; Peer reviewed
Post-Li batteries: promises and challenges
Current societal challenges in terms of energy storage have prompted an intensification in the research aiming at unravelling new high energy density battery technologies. These would have the potential of having disruptive effects in the world transition towards a less carbon-dependent energy economy through transport, both by electrification and renewable energy integration. Aside from controversial debates on lithium supply, the development of new sustainable battery chemistries based on abundant elements is appealing, especially for large-scale stationary applications. Interesting alternatives are to use sodium, magnesium or calcium instead of lithium. While for the Na-ion case, fast progresses are expected as a result of chemical similarities with lithium and the cumulated Li-ion battery know-how over the years, for Ca and Mg the situation is radically different. On the one hand, the possibility to use Ca or Mg metal anodes would bring a breakthrough in terms of energy density; on the other, development of suitable electrolytes and cathodes with efficient multivalent ion migration are bottlenecks to overcome. ; Funding from the European Union’s Horizon 2020 research and innovation programme is acknowledged, both from the European Research Council (A. Ponrouch ERC-2016-STG, CAMBAT grant agreement no. 715087) and FETOPEN-1-2016-2017 (CARBAT, grant agreement no. 766617). Acknowledgements. Authors acknowledge ALISTORE-ERI members and NAIADES (H2020, 646433) partners for helpful discussions and are grateful to Fanny Barde (Toyota Motor Europe) and M. Elena Arroyo-de Dompablo for fruitful collaboration. Authors are grateful to Ministry of Science, Innovation and Universities for support through MAT2017-86616-R and ‘Severo Ochoa’ Programme for Centres of Excellence in R&D (SEV-2015-0496). ; Peer reviewed
Post-Li batteries: promises and challenges
Ponrouch, Alexandre (author) / Palacín, M. Rosa (author) / European Research Council / European Commission / Ministerio de Ciencia, Innovación y Universidades (España) / Ministerio de Economía, Industria y Competitividad (España) / Ponrouch, Alexandre 0000-0002-8232-6324 / Palacín, M. Rosa 0000-0001-7351-2005
2019-07-08
Article (Journal)
Electronic Resource
English
DDC:
690
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