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    New developments in low clinker cement paste mineralogy

    The use of industrial waste as a cement addition often changes the composition and development of the hydrated phases and with them matrix performance and durability, in particular at later ages. The effect of the presence in blended cement of 20% to 50% kaolinite based activated carbon waste (ACW) on paste hydration has been characterized by means of XRD, SEM/EDX, TG/DTG, NMR and FTIR to identify and monitor the mineralogical phases forming in materials at ages of up to 180 d. The results showed that the main reaction products forming in the first 7 d included C-S-H gels, C4ACH12 and C4AH13 (hydroxy-AFm). Whilst monocarboaluminate (Mc) content declined with rising percentages of ACW, the amount of hexagonal phase hydroxy-AFm rose. Then microstructure of the C-S-H gels developing in the OPC and the 50% additioned paste differed. Compact C-S-H gel plates, and phyllosilicate-like laminar spongy microplates with high polymerised C-S-H gel formed in the blended cement paste. ; Peer Reviewed ; Postprint (author's final draft)

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    New developments in low clinker cement paste mineralogy

    The use of industrial waste as a cement addition often changes the composition and development of the hydrated phases and with them matrix performance and durability, in particular at later ages. The effect of the presence in blended cement of 20% to 50% kaolinite based activated carbon waste (ACW) on paste hydration has been characterized by means of XRD, SEM/EDX, TG/DTG, NMR and FTIR to identify and monitor the mineralogical phases forming in materials at ages of up to 180 d. The results showed that the main reaction products forming in the first 7 d included C-S-H gels, C4ACH12 and C4AH13 (hydroxy-AFm). Whilst monocarboaluminate (Mc) content declined with rising percentages of ACW, the amount of hexagonal phase hydroxy-AFm rose. Then microstructure of the C-S-H gels developing in the OPC and the 50% additioned paste differed. Compact C-S-H gel plates, and phyllosilicate-like laminar spongy microplates with high polymerised C-S-H gel formed in the blended cement paste. ; Peer Reviewed ; Postprint (author's final draft)

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    Download

    New developments in low clinker cement paste mineralogy

    The use of industrial waste as a cement addition often changes the composition and development of the hydrated phases and with them matrix performance and durability, in particular at later ages. The effect of the presence in blended cement of 20% to 50% kaolinite based activated carbon waste (ACW) on paste hydration has been characterized by means of XRD, SEM/EDX, TG/DTG, NMR and FTIR to identify and monitor the mineralogical phases forming in materials at ages of up to 180 d. The results showed that the main reaction products forming in the first 7 d included C-S-H gels, C4ACH12 and C4AH13 (hydroxy-AFm). Whilst monocarboaluminate (Mc) content declined with rising percentages of ACW, the amount of hexagonal phase hydroxy-AFm rose. Then microstructure of the C-S-H gels developing in the OPC and the 50% additioned paste differed. Compact C-S-H gel plates, and phyllosilicate-like laminar spongy microplates with high polymerised C-S-H gel formed in the blended cement paste. ; Peer Reviewed ; Postprint (author's final draft)

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    Title:

    New developments in low clinker cement paste mineralogy

    Contributors:

    Frias Rojas, Moisés (author) / Vigil de la Villa, Raquel (author) / Garcia, Rosario (author) / Martínez Ramírez, Sagrario (author) / Fernández Carrasco, Lucía (author) / Universitat Politècnica de Catalunya. Departament d'Enginyeria Civil i Ambiental / Universitat Politècnica de Catalunya. LiTA - Laboratori d'Innovació i Tecnologia en l'Arquitectura

    Publication date:

    2018-12-01

    DOI:

    https://doi.org/10.1016/j.clay.2018.09.009

    Type of media:

    Article (Journal)

    Type of material:

    Electronic Resource

    Language:

    English

    Keywords:

    Cement--Additives , Ciment -- Additius , Mineralogy Hydrated phases Activated clay waste Blended cement , Àrees temàtiques de la UPC::Enginyeria civil::Materials i estructures::Materials i estructures de formigó

    Classification:

    DDC:  710

    Licence:

    http://creativecommons.org/licenses/by-nc-nd/3.0/es/

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