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Physicochemical and Piezoresistive properties of smart cementitious composites with graphene nanoplates and graphite plates
Highlights Absorbances of GNP and GP solutions by ultrasonication were much higher that by mechanical stirring. A sudden electrical resistivity reduction was observed in GNP/cement composites with higher GNP dosage. Mechanical properties of GNP/cement composites firstly increased and then decreased with the GNP dosage. Both the GNP/cement- and GP/cement composites exhibited excellent electrical resistivity stability. GP/cement composites exhibited excellent piezoresistive repeatability except the GP is more than 2%.
Abstract Graphene nanoplate (GNP) and graphite plate (GP) are promising functional nanofillers for smart self-sensing cementitious composites. The effects of GNP and GP on physicochemical, mechanical and piezoresistive properties of cementitious composite were investigated in this paper. The results show that cement hydration was accelerated with the increased amounts of GNP and GP because of nucleation effect. The electrical resistivity of GNP-cementitious composites was always lower than the counterpart with GP with the same concentration. On the other hand, percolation occurred for the GNP/cementitious composites at the dosages from 2 to 3% (by weight), while it never happens for the GP/cementitious composites. Moreover, the GNP/cementitious composites reached the maximum mechanical strength when the GNP content was 1.0%, while for the GP/cementitious composites, only minor strength improvement was obtained with a dosage of 0.5% GP. As for the piezoresistivity, the cementitious composites with GNP exhibited higher fractional changes of resistivity. Irreversible resistivity happened for 2–3% GP/cementitious composites subjected to cyclic compression, due to the poor and loose microstructures. The outcomes are expected to provide an insight into the application of GNP/cementitious and GP/cement composites as cement-based sensors for the future structural health monitoring.
Physicochemical and Piezoresistive properties of smart cementitious composites with graphene nanoplates and graphite plates
Highlights Absorbances of GNP and GP solutions by ultrasonication were much higher that by mechanical stirring. A sudden electrical resistivity reduction was observed in GNP/cement composites with higher GNP dosage. Mechanical properties of GNP/cement composites firstly increased and then decreased with the GNP dosage. Both the GNP/cement- and GP/cement composites exhibited excellent electrical resistivity stability. GP/cement composites exhibited excellent piezoresistive repeatability except the GP is more than 2%.
Abstract Graphene nanoplate (GNP) and graphite plate (GP) are promising functional nanofillers for smart self-sensing cementitious composites. The effects of GNP and GP on physicochemical, mechanical and piezoresistive properties of cementitious composite were investigated in this paper. The results show that cement hydration was accelerated with the increased amounts of GNP and GP because of nucleation effect. The electrical resistivity of GNP-cementitious composites was always lower than the counterpart with GP with the same concentration. On the other hand, percolation occurred for the GNP/cementitious composites at the dosages from 2 to 3% (by weight), while it never happens for the GP/cementitious composites. Moreover, the GNP/cementitious composites reached the maximum mechanical strength when the GNP content was 1.0%, while for the GP/cementitious composites, only minor strength improvement was obtained with a dosage of 0.5% GP. As for the piezoresistivity, the cementitious composites with GNP exhibited higher fractional changes of resistivity. Irreversible resistivity happened for 2–3% GP/cementitious composites subjected to cyclic compression, due to the poor and loose microstructures. The outcomes are expected to provide an insight into the application of GNP/cementitious and GP/cement composites as cement-based sensors for the future structural health monitoring.
Physicochemical and Piezoresistive properties of smart cementitious composites with graphene nanoplates and graphite plates
Dong, Wenkui (author) / Li, Wengui (author) / Wang, Kejin (author) / Shah, Surendra P. (author)
2021-03-02
Article (Journal)
Electronic Resource
English
| British Library Online Contents | 2017
Piezoresistive Properties of Cementitious Composites Reinforced by PVA Fibres
| Springer Verlag | 2017