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An investigation of the phosphate removal mechanism by MgFe layered double hydroxides
https://orcid.org/0000-0003-1377-6644
https://orcid.org/0000-0002-2336-3061
Abstract The phosphate adsorption properties including kinetics and uptake pathway of MgxFe layered double hydroxides (LDH) with targeted x values of 2 and 3 and intercalated with nitrate (NO3 −) and chloride (Cl−) anions were investigated at a phosphate concentration of 16.31 mgP·L−1 and pH (pH = 5, 7, and 9) similar to wastewater conditions. The synthesized MgxFe-LDH show fast adsorption (90–98%) of the final phosphate removal within 3 h and remove 68–73% of the total phosphate content after 24 h. The pristine MgxFe-LDH and solid products after phosphate exposure were characterized by PXRD, FT-IR, zeta-potential, SEM, and solid-state 31P MAS NMR spectroscopy to investigate the phosphate removal pathway. Interestingly, the four MgxFe-LDH phase had similar Mg:Fe ratios irrespective of the Mg:Fe ratio of the reactants based on PXRD. The MgxFe-LDH plate-like morphology was preserved after phosphate exposure and no sign of phosphate intercalation were evident by PXRD, FT-IR, and SEM albeit a small amount of the MgxFe LDH was dissolved based on ICP-OES, PXRD and the final pH. Partial dissolution of the LDH was clearly evident by SEM for Mg2Fe-LDH exposed to 200% theoretical P capacity. The FT-IR spectra and zeta-potential values indicated that the phosphate ions are adsorbed by surface complexation. The 31P MAS NMR spectra of MgxFe-LDH exposed to phosphate has an intense spinning sideband manifold and only minor paramagnetic shifts (<30 ppm) are observed. Thus, phosphate is in the proximity of iron, but not directly bound to the paramagnetic iron via Fe-O-P bond (inner-sphere complexation or mineralization). Thus, the dominating phosphate uptake pathway by MgxFe-LDH is surface complexation similar to MgAl-LDH and possible the formation of ill-defined magnesium phosphate due to partial dissolution of the MgFe-LDH, especially at high P loading.
Graphical abstract Display Omitted
Highlights Phosphate removal by MgFe-LDH studied at P concentration and pH in wastewater. MgFe-LDH show fast adsorption within 3 h. MgFe-LDH crystal structure and morphology was preserved after phosphate adsorption. Outer-sphere complexation on LDH surface is the dominating phosphate uptake pathway.
An investigation of the phosphate removal mechanism by MgFe layered double hydroxides
https://orcid.org/0000-0003-1377-6644
https://orcid.org/0000-0002-2336-3061
Abstract The phosphate adsorption properties including kinetics and uptake pathway of MgxFe layered double hydroxides (LDH) with targeted x values of 2 and 3 and intercalated with nitrate (NO3 −) and chloride (Cl−) anions were investigated at a phosphate concentration of 16.31 mgP·L−1 and pH (pH = 5, 7, and 9) similar to wastewater conditions. The synthesized MgxFe-LDH show fast adsorption (90–98%) of the final phosphate removal within 3 h and remove 68–73% of the total phosphate content after 24 h. The pristine MgxFe-LDH and solid products after phosphate exposure were characterized by PXRD, FT-IR, zeta-potential, SEM, and solid-state 31P MAS NMR spectroscopy to investigate the phosphate removal pathway. Interestingly, the four MgxFe-LDH phase had similar Mg:Fe ratios irrespective of the Mg:Fe ratio of the reactants based on PXRD. The MgxFe-LDH plate-like morphology was preserved after phosphate exposure and no sign of phosphate intercalation were evident by PXRD, FT-IR, and SEM albeit a small amount of the MgxFe LDH was dissolved based on ICP-OES, PXRD and the final pH. Partial dissolution of the LDH was clearly evident by SEM for Mg2Fe-LDH exposed to 200% theoretical P capacity. The FT-IR spectra and zeta-potential values indicated that the phosphate ions are adsorbed by surface complexation. The 31P MAS NMR spectra of MgxFe-LDH exposed to phosphate has an intense spinning sideband manifold and only minor paramagnetic shifts (<30 ppm) are observed. Thus, phosphate is in the proximity of iron, but not directly bound to the paramagnetic iron via Fe-O-P bond (inner-sphere complexation or mineralization). Thus, the dominating phosphate uptake pathway by MgxFe-LDH is surface complexation similar to MgAl-LDH and possible the formation of ill-defined magnesium phosphate due to partial dissolution of the MgFe-LDH, especially at high P loading.
Graphical abstract Display Omitted
Highlights Phosphate removal by MgFe-LDH studied at P concentration and pH in wastewater. MgFe-LDH show fast adsorption within 3 h. MgFe-LDH crystal structure and morphology was preserved after phosphate adsorption. Outer-sphere complexation on LDH surface is the dominating phosphate uptake pathway.
An investigation of the phosphate removal mechanism by MgFe layered double hydroxides
https://orcid.org/0000-0003-1377-6644
https://orcid.org/0000-0002-2336-3061
Abstract The phosphate adsorption properties including kinetics and uptake pathway of MgxFe layered double hydroxides (LDH) with targeted x values of 2 and 3 and intercalated with nitrate (NO3 −) and chloride (Cl−) anions were investigated at a phosphate concentration of 16.31 mgP·L−1 and pH (pH = 5, 7, and 9) similar to wastewater conditions. The synthesized MgxFe-LDH show fast adsorption (90–98%) of the final phosphate removal within 3 h and remove 68–73% of the total phosphate content after 24 h. The pristine MgxFe-LDH and solid products after phosphate exposure were characterized by PXRD, FT-IR, zeta-potential, SEM, and solid-state 31P MAS NMR spectroscopy to investigate the phosphate removal pathway. Interestingly, the four MgxFe-LDH phase had similar Mg:Fe ratios irrespective of the Mg:Fe ratio of the reactants based on PXRD. The MgxFe-LDH plate-like morphology was preserved after phosphate exposure and no sign of phosphate intercalation were evident by PXRD, FT-IR, and SEM albeit a small amount of the MgxFe LDH was dissolved based on ICP-OES, PXRD and the final pH. Partial dissolution of the LDH was clearly evident by SEM for Mg2Fe-LDH exposed to 200% theoretical P capacity. The FT-IR spectra and zeta-potential values indicated that the phosphate ions are adsorbed by surface complexation. The 31P MAS NMR spectra of MgxFe-LDH exposed to phosphate has an intense spinning sideband manifold and only minor paramagnetic shifts (<30 ppm) are observed. Thus, phosphate is in the proximity of iron, but not directly bound to the paramagnetic iron via Fe-O-P bond (inner-sphere complexation or mineralization). Thus, the dominating phosphate uptake pathway by MgxFe-LDH is surface complexation similar to MgAl-LDH and possible the formation of ill-defined magnesium phosphate due to partial dissolution of the MgFe-LDH, especially at high P loading.
Graphical abstract Display Omitted
Highlights Phosphate removal by MgFe-LDH studied at P concentration and pH in wastewater. MgFe-LDH show fast adsorption within 3 h. MgFe-LDH crystal structure and morphology was preserved after phosphate adsorption. Outer-sphere complexation on LDH surface is the dominating phosphate uptake pathway.
An investigation of the phosphate removal mechanism by MgFe layered double hydroxides
Kim, Tae-Hyun (author) / Lundehøj, Laura (author) / Nielsen, Ulla Gro (author)
Applied Clay Science ; 189
2020-02-17
Article (Journal)
Electronic Resource
English
| Wiley | 2020
Adsorption of phosphate by layered double hydroxides in aqueous solutions
| Online Contents | 2006