Mineralogical characterisation and surface properties of sepiolite from Polatli (Turkey): Fid-Bau Portal

Mineralogical characterisation and surface properties of sepiolite from Polatli (Turkey)

Suárez, M. / García-Rivas, J. / García-Romero, E. / Jara, N.

Abstract Sepiolite is one of the most important industrial minerals, due primarily to its surface properties related to its structure. Sepiolite contains alternating 2:1 polysomes that produce tunnels at the inner part of the fibre and channels at the edge of the fibre. Sepiolite is a mineral with notably wide variations in the crystal-chemistry, crystallinity and texture, depending on the formation conditions, which results in highly different characteristics and properties. In this work, six sepiolite samples from the Polatli area (Turkey) are studied, comparing their mineralogical and textural features. The mineralogical composition of the samples is similar: carbonates constitute the main impurities, dolomite appears in all samples studied in different proportions, and small amounts of calcite, quartz and palygorskite have been identified. There is a variation in almost all the reflections of sepiolite, the 110 d-spacing ranges between 12.31Å and 12.05Å, this variation is related to the crystal-chemistry of the mineral. The impurities are clearly identified in the IR spectra, in which in addition to the carbonates the presence of the palygorskite polysomes is also detected by the band located at ~3620cm⁻¹. The differences in the surface properties found in this study (specific surface area between 122m² g⁻¹ and 376m² g⁻¹ and microporous area between 55m² g⁻¹ and 168m² g⁻¹) cannot be related only with the content in impurities, but with the texture and the possible presence of intergrowths.

Highlights • The six sepiolites studied show high variability both in their mineralogical and surface properties that cannot be explained only by the impurities. • XRD show differences both in sepiolite peak position as in width indicating differences in the cell parameters related to the crystal-chemical variations. • The variations in the surface properties of the sepiolite are mainly related to the presence of impurities, the texture, and the intergrowths.