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Hydroxyl radical from the reaction between hypochlorite and hydrogen peroxide
AbstractWe studied the reaction between hypochlorite anion (−OCl) and hydrogen peroxide (H2O2) by using spin-trapping agents such as 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) and 5-diethoxy-phosphoryl-5-methyl-1-pyrroline-N-oxide (DEPMPO). The obtained data demonstrate that hydroxyl radical is produced in this reaction. Thus, −OCl and H2O2 could assume new relevance in environmental chemistry by representing a potential source of hydroxyl radicals and other oxidant species, such as HO–OCl and OCl radical.
Hydroxyl radical from the reaction between hypochlorite and hydrogen peroxide
AbstractWe studied the reaction between hypochlorite anion (−OCl) and hydrogen peroxide (H2O2) by using spin-trapping agents such as 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) and 5-diethoxy-phosphoryl-5-methyl-1-pyrroline-N-oxide (DEPMPO). The obtained data demonstrate that hydroxyl radical is produced in this reaction. Thus, −OCl and H2O2 could assume new relevance in environmental chemistry by representing a potential source of hydroxyl radicals and other oxidant species, such as HO–OCl and OCl radical.
Hydroxyl radical from the reaction between hypochlorite and hydrogen peroxide
Castagna, Riccardo (author) / Eiserich, Jason P. (author) / Budamagunta, Madhu S. (author) / Stipa, Pierluigi (author) / Cross, Carroll E. (author) / Proietti, Elisa (author) / Voss, John C. (author) / Greci, Lucedio (author)
Atmospheric Environment ; 42 ; 6551-6554
2008-04-23
4 pages
Article (Journal)
Electronic Resource
English
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