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Hydrogenation of 4-vinylcyclohex-1-ene in the presence of rhodium complexes

Shebaldova, A.D. / Bystrenina, V.I. / Kravtsova, V.N. / Khidekel, M.L.

Abstract 4-Vinylcyclohex-1-ene was hydrogenated in the presence of rhodium complexes with various ligands (acetylacetone, triphenylphosphine, fluorescein and aromatic disulphoacids). It was established that with the absorption of 1 mole hydrogen the yield of ethylcyclohexene is 99%. A study was made of the dependence on solvent and temperature of the rate of hydrogenation of 4-vinylcyclohex-1-ene in the presence of Rh-fluorescein.

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Hydrogenation of 4-vinylcyclohex-1-ene in the presence of rhodium complexes

Shebaldova, A.D. / Bystrenina, V.I. / Kravtsova, V.N. / Khidekel, M.L.

Abstract 4-Vinylcyclohex-1-ene was hydrogenated in the presence of rhodium complexes with various ligands (acetylacetone, triphenylphosphine, fluorescein and aromatic disulphoacids). It was established that with the absorption of 1 mole hydrogen the yield of ethylcyclohexene is 99%. A study was made of the dependence on solvent and temperature of the rate of hydrogenation of 4-vinylcyclohex-1-ene in the presence of Rh-fluorescein.

Hydrogenation of 4-vinylcyclohex-1-ene in the presence of rhodium complexes

Shebaldova, A.D. / Bystrenina, V.I. / Kravtsova, V.N. / Khidekel, M.L.

Abstract 4-Vinylcyclohex-1-ene was hydrogenated in the presence of rhodium complexes with various ligands (acetylacetone, triphenylphosphine, fluorescein and aromatic disulphoacids). It was established that with the absorption of 1 mole hydrogen the yield of ethylcyclohexene is 99%. A study was made of the dependence on solvent and temperature of the rate of hydrogenation of 4-vinylcyclohex-1-ene in the presence of Rh-fluorescein.

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Title:

Hydrogenation of 4-vinylcyclohex-1-ene in the presence of rhodium complexes

Contributors:

Shebaldova, A.D. (author) / Bystrenina, V.I. (author) / Kravtsova, V.N. (author) / Khidekel, M.L. (author)

Published in:

Petroleum Chemistry: USSR (English Translation of Neftekhimiya) ; 15 ; 137-140

Publication date:

1974-12-01

Size:

4 pages

ISSN:

DOI:

https://doi.org/10.1016/0031-6458(75)90018-0

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

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