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Particle size distributions of currently used pesticides in ambient air of an agricultural Mediterranean area
Abstract This work presents first data on the particle size distribution of 16 pesticides currently used in Mediterranean agriculture in the atmosphere. Particulate matter air samples were collected using a cascade impactor distributed into four size fractions in a rural site of Valencia Region, during July to September in 2012 and from May to July in 2013. A total of 16 pesticides were detected, including six fungicides, seven insecticides and three herbicides. The total concentrations in the particulate phase (TSP: Total Suspended Particulate) ranged from 3.5 to 383.1 pg m−3. Most of the pesticides (such as carbendazim, tebuconazole, chlorpyrifos-ethyl and chlorpyrifos-methyl) were accumulated in the ultrafine-fine (<1 μm) and coarse (2.5–10 μm) particle size fractions. Others like omethoate, dimethoate and malathion were presented only in the ultrafine-fine size fraction (<1 μm). Finally, diuron, diphenylamine and terbuthylazine-desethyl-2-OH also show a bimodal distribution but mainly in the coarse size fractions.
Highlights Particle size distribution of pesticides in Mediterranean agriculture was studied. Pesticides accumulated in the ultrafine-fine and coarse particle size fractions. The total concentrations in the particulate phase ranged from 3.5 to 383.1 pg m−3.
Particle size distributions of currently used pesticides in ambient air of an agricultural Mediterranean area
Abstract This work presents first data on the particle size distribution of 16 pesticides currently used in Mediterranean agriculture in the atmosphere. Particulate matter air samples were collected using a cascade impactor distributed into four size fractions in a rural site of Valencia Region, during July to September in 2012 and from May to July in 2013. A total of 16 pesticides were detected, including six fungicides, seven insecticides and three herbicides. The total concentrations in the particulate phase (TSP: Total Suspended Particulate) ranged from 3.5 to 383.1 pg m−3. Most of the pesticides (such as carbendazim, tebuconazole, chlorpyrifos-ethyl and chlorpyrifos-methyl) were accumulated in the ultrafine-fine (<1 μm) and coarse (2.5–10 μm) particle size fractions. Others like omethoate, dimethoate and malathion were presented only in the ultrafine-fine size fraction (<1 μm). Finally, diuron, diphenylamine and terbuthylazine-desethyl-2-OH also show a bimodal distribution but mainly in the coarse size fractions.
Highlights Particle size distribution of pesticides in Mediterranean agriculture was studied. Pesticides accumulated in the ultrafine-fine and coarse particle size fractions. The total concentrations in the particulate phase ranged from 3.5 to 383.1 pg m−3.
Particle size distributions of currently used pesticides in ambient air of an agricultural Mediterranean area
Coscollà, Clara (author) / Muñoz, Amalia (author) / Borrás, Esther (author) / Vera, Teresa (author) / Ródenas, Milagros (author) / Yusà, Vicent (author)
Atmospheric Environment ; 95 ; 29-35
2014-06-10
7 pages
Article (Journal)
Electronic Resource
English