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Synthesis, stereochemistry and isomeric transformations of 6,7-dimethylbicyclo[3.2.1]octane

Matveyeva, I.A. / Sokolova, I.M. / Pekhk, T.I. / Petrov, Al.A.

Abstract 1. 1. 6.7-Dimethylbicyclo[3.2.1]octane was synthesized, which had not been described previously in the literature. 2. 2. Ratios of geomers and their steric structure were determined by configuration isomerization. 3. 3. Kinetic and mechanism of isomerization of 6,7-dimethylbicyclo[3.2.1]octane were investigated in the presence of aluminium bromide. Low rates of conversion due to steric hindrances of ionization are a distinctive feature of isomerization of dimethylbicyclo[3.2.1]octanes.

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Synthesis, stereochemistry and isomeric transformations of 6,7-dimethylbicyclo[3.2.1]octane

Matveyeva, I.A. / Sokolova, I.M. / Pekhk, T.I. / Petrov, Al.A.

Abstract 1. 1. 6.7-Dimethylbicyclo[3.2.1]octane was synthesized, which had not been described previously in the literature. 2. 2. Ratios of geomers and their steric structure were determined by configuration isomerization. 3. 3. Kinetic and mechanism of isomerization of 6,7-dimethylbicyclo[3.2.1]octane were investigated in the presence of aluminium bromide. Low rates of conversion due to steric hindrances of ionization are a distinctive feature of isomerization of dimethylbicyclo[3.2.1]octanes.

Synthesis, stereochemistry and isomeric transformations of 6,7-dimethylbicyclo[3.2.1]octane

Matveyeva, I.A. / Sokolova, I.M. / Pekhk, T.I. / Petrov, Al.A.

Abstract 1. 1. 6.7-Dimethylbicyclo[3.2.1]octane was synthesized, which had not been described previously in the literature. 2. 2. Ratios of geomers and their steric structure were determined by configuration isomerization. 3. 3. Kinetic and mechanism of isomerization of 6,7-dimethylbicyclo[3.2.1]octane were investigated in the presence of aluminium bromide. Low rates of conversion due to steric hindrances of ionization are a distinctive feature of isomerization of dimethylbicyclo[3.2.1]octanes.

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Title:

Synthesis, stereochemistry and isomeric transformations of 6,7-dimethylbicyclo[3.2.1]octane

Contributors:

Matveyeva, I.A. (author) / Sokolova, I.M. (author) / Pekhk, T.I. (author) / Petrov, Al.A. (author)

Published in:

Petroleum Chemistry: USSR (English Translation of Neftekhimiya) ; 15 ; 160-165

Publication date:

1975-01-10

Size:

6 pages

ISSN:

DOI:

https://doi.org/10.1016/0031-6458(75)90023-4

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

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