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Removal of Acid Green 68:1 from aqueous solutions by calcined and uncalcined layered double hydroxides
Abstract Magnesium aluminum layered double hydroxide (LDH) was synthesized by the co-precipitation method followed by calcination. The resulting materials were characterized by X-ray diffraction (PXRD) and attenuated total reflectance with Fourier transform infrared spectroscopy (FTIR/ATR) and simultaneous thermogravimetric analysis/differential scanning calorimetry coupled to mass spectrometry (TGA–DSC–MS). Calcined and non-calcined LDHs were used as adsorbents to remove azo dye Acid Green 68:1 in an aqueous solution. Adsorption experiment results indicated that calcined LDH possesses greater adsorption capacity (154.8mgg−1) than non-calcined LDH (99.1mgg−1). Isotherms showed that adsorption of the dye was more consistent with the Langmuir model. Kinetic experiments of calcined LDH adsorption showed that for low concentration (50, 100 and 200mgL−1), the system reached the adsorption equilibrium in 1, 2, and 4h, and for higher concentration after 10h. The best kinetic model was the pseudo-second order. Adsorption studies also showed that the capacity for adsorption of the dye by calcinated LDH does not significantly diminish with pH level variation.
Highlights Calcined layered double hydroxide (CLDH) exhibited high capacity to adsorption. The adsorption capacity by CLDH did not diminish with variation in pH levels. The adsorption of the dye was consistent with the Langmuir model.
Removal of Acid Green 68:1 from aqueous solutions by calcined and uncalcined layered double hydroxides
Abstract Magnesium aluminum layered double hydroxide (LDH) was synthesized by the co-precipitation method followed by calcination. The resulting materials were characterized by X-ray diffraction (PXRD) and attenuated total reflectance with Fourier transform infrared spectroscopy (FTIR/ATR) and simultaneous thermogravimetric analysis/differential scanning calorimetry coupled to mass spectrometry (TGA–DSC–MS). Calcined and non-calcined LDHs were used as adsorbents to remove azo dye Acid Green 68:1 in an aqueous solution. Adsorption experiment results indicated that calcined LDH possesses greater adsorption capacity (154.8mgg−1) than non-calcined LDH (99.1mgg−1). Isotherms showed that adsorption of the dye was more consistent with the Langmuir model. Kinetic experiments of calcined LDH adsorption showed that for low concentration (50, 100 and 200mgL−1), the system reached the adsorption equilibrium in 1, 2, and 4h, and for higher concentration after 10h. The best kinetic model was the pseudo-second order. Adsorption studies also showed that the capacity for adsorption of the dye by calcinated LDH does not significantly diminish with pH level variation.
Highlights Calcined layered double hydroxide (CLDH) exhibited high capacity to adsorption. The adsorption capacity by CLDH did not diminish with variation in pH levels. The adsorption of the dye was consistent with the Langmuir model.
Removal of Acid Green 68:1 from aqueous solutions by calcined and uncalcined layered double hydroxides
dos Santos, Rodrigo Morais Menezes (author) / Gonçalves, Rosembergue Gabriel Lima (author) / Constantino, Vera Regina Leopoldo (author) / da Costa, Liovando Marciano (author) / da Silva, Luis Henrique Mendes (author) / Tronto, Jairo (author) / Pinto, Frederico Garcia (author)
Applied Clay Science ; 80-81 ; 189-195
2013-04-18
7 pages
Article (Journal)
Electronic Resource
English