A platform for research: civil engineering, architecture and urbanism
A platform for research: civil engineering, architecture and urbanism
Chromate intercalation in Ni–Zn layered hydroxide salts
AbstractAn acetate-intercalated Ni–Zn layered hydroxide salt (LHS) was exchanged with chromate anions, achieving a rather large oxometalate concentration, which almost completely balanced the positive charges of the layers, as concluded from element chemical analysis, powder X-ray diffraction, and FT-IR spectroscopy results.Thermal decomposition of the solid led to dehydration and chromate anion grafting, followed by dehydroxylation of the host and reduction of the chromate anions. The solid then lost the layer structure, forming solids with large micro and mesoporosity, which corresponded to poorly crystallized (Zn, Ni)–Cr spinels, as well as nickel and zinc oxides.
Chromate intercalation in Ni–Zn layered hydroxide salts
AbstractAn acetate-intercalated Ni–Zn layered hydroxide salt (LHS) was exchanged with chromate anions, achieving a rather large oxometalate concentration, which almost completely balanced the positive charges of the layers, as concluded from element chemical analysis, powder X-ray diffraction, and FT-IR spectroscopy results.Thermal decomposition of the solid led to dehydration and chromate anion grafting, followed by dehydroxylation of the host and reduction of the chromate anions. The solid then lost the layer structure, forming solids with large micro and mesoporosity, which corresponded to poorly crystallized (Zn, Ni)–Cr spinels, as well as nickel and zinc oxides.
Chromate intercalation in Ni–Zn layered hydroxide salts
Rojas, Ricardo (author) / Ulibarri, M. Ángeles (author) / Barriga, Cristobalina (author) / Rives, Vicente (author)
Applied Clay Science ; 49 ; 176-181
2010-04-28
6 pages
Article (Journal)
Electronic Resource
English
Chromate intercalation in Ni–Zn layered hydroxide salts
| Online Contents | 2010
Intercalation of Tetracyanoquinodimethane in [Zn-Al] Layered Double Hydroxide
| British Library Online Contents | 1998
In situ synthesis of polyelectrolyte/layered double hydroxide intercalation compounds
| British Library Online Contents | 2017