Preparation and properties of halogen-free flame-retardant layered silicate-polyamide 66 nanocomposites: Fid-Bau Portal

Preparation and properties of halogen-free flame-retardant layered silicate-polyamide 66 nanocomposites

Tamura, Kenji / Ohyama, Shoichi / Umeyama, Kiyoshi / Kitazawa, Takafumi / Yamagishi, Akihiko

Abstract The relationship between the morphology, flammability and mechanical properties of layered silicate-polyamide 66 (PA66) nanocomposites was investigated. The nanocomposites were composed of PA66, melamine-modified layered silicate (MLS) as a nanofiller, and/or melamine cyanurate (MC). Samples of MLS with different dispersion states were obtained by changing the melt-mixing procedures for PA66, MLS and MC. X-ray diffraction (XRD), transmission electron microscopy (TEM), thermal analysis, strength tests, cone calorimetry tests and UL 94 vertical burning tests were used to examine the effects of MLS on the morphology, mechanical properties and flame resistance performance of the materials. The data revealed a correlation between the dispersion state of the MLS layers and flame retardancy. The nanocomposite manufactured by one-stage kneading of a mixture of PA66, MLS and MC earned a UL 94 rating of V0. The flame retardancy of dripping particles during combustion was found to be due to uneven dispersion of MLS in the PA66 matrix.

Graphical abstract The results revealed a correlation between the dispersion state of the clay mineral layers and flame retardancy. S-3 has good flame-retardant properties and high mechanical performance. Display Omitted

Highlights • Halogen-free flame retardant PA66 nanocomposites were prepared. • Melamine-modified layered silicate and/or melamine cyanurate were used. • The CPN were prepared by changing the compounding procedures. • The CPN manufactured by one-stage kneading was given a UL 94 rating of V0. • The CPN also have high mechanical performance.