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Crystallographic, vibrational, thermal and electrochemical properties of nacrite-NH4Cl nanohybrid
AbstractSi2Al2O5(OH)4·(1−χ)NH4Cl·(1−χ)H2O nanohybrid was prepared by indirect intercalation of ammonium chloride into the interlamellar space of nacrite. The number and position of intercalated ions and water molecules, the layer thicknesses, the stacking mode along the normal to the layer plane (z) were determined by modelling X-ray diffraction patterns. Infrared spectroscopy was carried out to observe the interactions between the silicate “network” and the ammonium chloride salt. Thermogravimetric analysis was achieved to study the phase transition of the nanohybrid when the system temperature is increased. Finally, the electrochemical identification of the new nanohybrid material was performed with both parameters: frequency and temperature. Indeed, the prepared compound has a fairly high ionic conductivity at higher temperatures and can be classified as a superionic conductor.
Graphical abstract
HighlightsTwo-step hybridization process of NH4Cl into the nacrite interlayer spaceXRD analysis showed the z-coordinates and number of the inserted species.IR and TGA investigations confirmed the XRD results of the elaborated nanohybrid.High-temperature phase of the novel nanohybrid exhibits high ionic conductivity.
Crystallographic, vibrational, thermal and electrochemical properties of nacrite-NH4Cl nanohybrid
AbstractSi2Al2O5(OH)4·(1−χ)NH4Cl·(1−χ)H2O nanohybrid was prepared by indirect intercalation of ammonium chloride into the interlamellar space of nacrite. The number and position of intercalated ions and water molecules, the layer thicknesses, the stacking mode along the normal to the layer plane (z) were determined by modelling X-ray diffraction patterns. Infrared spectroscopy was carried out to observe the interactions between the silicate “network” and the ammonium chloride salt. Thermogravimetric analysis was achieved to study the phase transition of the nanohybrid when the system temperature is increased. Finally, the electrochemical identification of the new nanohybrid material was performed with both parameters: frequency and temperature. Indeed, the prepared compound has a fairly high ionic conductivity at higher temperatures and can be classified as a superionic conductor.
Graphical abstract
HighlightsTwo-step hybridization process of NH4Cl into the nacrite interlayer spaceXRD analysis showed the z-coordinates and number of the inserted species.IR and TGA investigations confirmed the XRD results of the elaborated nanohybrid.High-temperature phase of the novel nanohybrid exhibits high ionic conductivity.
Crystallographic, vibrational, thermal and electrochemical properties of nacrite-NH4Cl nanohybrid
Jaafar, Nouha (author) / Ben Rhaiem, Hafsia (author) / Ben Haj Amara, Abdesslem (author)
Applied Clay Science ; 132-133 ; 600-610
2016-08-08
11 pages
Article (Journal)
Electronic Resource
English
Crystallographic, vibrational, thermal and electrochemical properties of nacrite-NH4Cl nanohybrid
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