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The importance of specific surface area in the geopolymerization of heated illitic clay
AbstractGeopolymers are inorganic binders formed by adding alkaline (hydroxide) solution to silicates such as blast furnace slag, fly ash or calcined clay to dissolve Si and Al that polymerizes and precipitates while hardening. The most common clay used as geopolymer raw material is kaolin. The aim of this study was to investigate the suitability of clays dominated by 2:1 dioctahedral layer silicates using the example of Friedland clay as a cheaper alternative to kaolin and determine the necessary preparation steps required to produce an effective geopolymer binder material. After a Rietveld-based quantification of the raw clay, the successive thermal modifications of the mineral phases were analyzed using simultaneous thermal analysis coupled with mass spectrometer (STA-MS), temperature-resolved X-ray diffraction (TXRD), and 27Al solid-state nuclear magnetic resonance spectroscopy (NMR) measurements. Friedland clay heated to 875°C was found to produce a geopolymer with the highest compressive strength, but in contrast to the literature, the Si:Al ratio and the amount of 5-fold coordinated Al were not found to be the key parameters that determined the success of geopolymer synthesis. The specific surface area and the amount of Si and Al dissolved are here reported to be the key factors determining the suitability of clays dominated by 2:1 dioctahedral layer silicates as raw materials for geopolymer production.
HighlightsClays dominated by 2:1 dioctahedral phases are suitable as geopolymer raw materials.875°C heated Friedland clay produced a geopolymer with the highest compressive strength.Parameter dissolved Si+Al divided by the specific surface area explains compressive strength vs. temperature function.Amount of Al[5] and Si:Al ratio less important parameters for the GP reaction
The importance of specific surface area in the geopolymerization of heated illitic clay
AbstractGeopolymers are inorganic binders formed by adding alkaline (hydroxide) solution to silicates such as blast furnace slag, fly ash or calcined clay to dissolve Si and Al that polymerizes and precipitates while hardening. The most common clay used as geopolymer raw material is kaolin. The aim of this study was to investigate the suitability of clays dominated by 2:1 dioctahedral layer silicates using the example of Friedland clay as a cheaper alternative to kaolin and determine the necessary preparation steps required to produce an effective geopolymer binder material. After a Rietveld-based quantification of the raw clay, the successive thermal modifications of the mineral phases were analyzed using simultaneous thermal analysis coupled with mass spectrometer (STA-MS), temperature-resolved X-ray diffraction (TXRD), and 27Al solid-state nuclear magnetic resonance spectroscopy (NMR) measurements. Friedland clay heated to 875°C was found to produce a geopolymer with the highest compressive strength, but in contrast to the literature, the Si:Al ratio and the amount of 5-fold coordinated Al were not found to be the key parameters that determined the success of geopolymer synthesis. The specific surface area and the amount of Si and Al dissolved are here reported to be the key factors determining the suitability of clays dominated by 2:1 dioctahedral layer silicates as raw materials for geopolymer production.
HighlightsClays dominated by 2:1 dioctahedral phases are suitable as geopolymer raw materials.875°C heated Friedland clay produced a geopolymer with the highest compressive strength.Parameter dissolved Si+Al divided by the specific surface area explains compressive strength vs. temperature function.Amount of Al[5] and Si:Al ratio less important parameters for the GP reaction
The importance of specific surface area in the geopolymerization of heated illitic clay
Dietel, Jan (author) / Warr, Laurence N. (author) / Bertmer, Marko (author) / Steudel, Annett (author) / Grathoff, Georg H. (author) / Emmerich, Katja (author)
Applied Clay Science ; 139 ; 99-107
2017-01-03
9 pages
Article (Journal)
Electronic Resource
English
The importance of specific surface area in the geopolymerization of heated illitic clay
| Online Contents | 2017
The importance of specific surface area in the geopolymerization of heated illitic clay
| Online Contents | 2017
Geopolymerization of glass- and silicate-containing heated clay
| British Library Online Contents | 2018
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| British Library Online Contents | 2018
Geopolymerization of glass- and silicate-containing heated clay
| British Library Online Contents | 2018