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Dimerization of styrene with α-methylstyrene
Abstract 1. A study was made of dimerization of styrene and α-methylstyrene with phosphoric acid at 130 to 135° resulting in the formatiion of four theoretically possible cyclic hydrocarbons: 1-methyl-3-phnylindane, 1,3-dimethyl-1-phenylindane, l,l-dimethyl-3-phnylindane and 1,1,3-trimethyl-3-phenylindane. 2. Ions obtained from styrene and α-methylstyrene interact with styrene 2.1–2·8 and 1·3–3 times respectively more easily than with α-methylstyrene. As a results, l,l-dimethyl-3-phenylindane yield exceeds almost 4 times that of 1,3-dimethyl-1-phenylindane.
Dimerization of styrene with α-methylstyrene
Abstract 1. A study was made of dimerization of styrene and α-methylstyrene with phosphoric acid at 130 to 135° resulting in the formatiion of four theoretically possible cyclic hydrocarbons: 1-methyl-3-phnylindane, 1,3-dimethyl-1-phenylindane, l,l-dimethyl-3-phnylindane and 1,1,3-trimethyl-3-phenylindane. 2. Ions obtained from styrene and α-methylstyrene interact with styrene 2.1–2·8 and 1·3–3 times respectively more easily than with α-methylstyrene. As a results, l,l-dimethyl-3-phenylindane yield exceeds almost 4 times that of 1,3-dimethyl-1-phenylindane.
Dimerization of styrene with α-methylstyrene
Volkov, R.N. (author) / Tsybin, Yu.S. (author) / Kuzenkov, V.V. (author)
1965-09-15
6 pages
Article (Journal)
Electronic Resource
English
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