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Comparison of corrosion resistance mechanism between ordinary Portland concrete and alkali-activated concrete subjected to biogenic sulfuric acid attack
Highlights The corrosion mechanism of AAC and OPC by BSA was investigated. The number of bacteria attached to the surface of OPC is higher than that of AAC. The main corrosion product of OPC and AAC is gypsum. The corrosion of OPC is more serious than that of AAC.
Abstract The difference of corrosion resistance mechanism between alkali-activated concrete (AAC) and ordinary Portland cement concrete (OPC) under biogenic sulfuric acid corrosion was compared. By measuring the local surface morphology, mass loss, compressive strength and Ca2+ dissolution of OPC and AAC specimens, the corrosion resistance of these two kinds of concrete to biogenic sulfuric acid (BSA) was studied. The hydration products and corrosion products of OPC and AAC were studied with X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and environmental scanning electron microscopy-energy dispersive spectroscopy (ESEM-EDS). The results show that under BSA corrosion, the thickness, roughness and porosity of the corrosion layer of OPC are obviously greater than those of AAC. The main corrosion products of OPC and AAC is gypsum. The amount of gypsum produced on the surface of OPC corrosion layer is larger than that of AAC. In addition, the bacterial effect on the surface of AAC corrosion layer is greater than that of OPC, which makes the corrosion path of BSA shorter than that of OPC. Therefore, the corrosion resistance of AAC to BSA is better than that of OPC.
Comparison of corrosion resistance mechanism between ordinary Portland concrete and alkali-activated concrete subjected to biogenic sulfuric acid attack
Highlights The corrosion mechanism of AAC and OPC by BSA was investigated. The number of bacteria attached to the surface of OPC is higher than that of AAC. The main corrosion product of OPC and AAC is gypsum. The corrosion of OPC is more serious than that of AAC.
Abstract The difference of corrosion resistance mechanism between alkali-activated concrete (AAC) and ordinary Portland cement concrete (OPC) under biogenic sulfuric acid corrosion was compared. By measuring the local surface morphology, mass loss, compressive strength and Ca2+ dissolution of OPC and AAC specimens, the corrosion resistance of these two kinds of concrete to biogenic sulfuric acid (BSA) was studied. The hydration products and corrosion products of OPC and AAC were studied with X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and environmental scanning electron microscopy-energy dispersive spectroscopy (ESEM-EDS). The results show that under BSA corrosion, the thickness, roughness and porosity of the corrosion layer of OPC are obviously greater than those of AAC. The main corrosion products of OPC and AAC is gypsum. The amount of gypsum produced on the surface of OPC corrosion layer is larger than that of AAC. In addition, the bacterial effect on the surface of AAC corrosion layer is greater than that of OPC, which makes the corrosion path of BSA shorter than that of OPC. Therefore, the corrosion resistance of AAC to BSA is better than that of OPC.
Comparison of corrosion resistance mechanism between ordinary Portland concrete and alkali-activated concrete subjected to biogenic sulfuric acid attack
Xie, Yudong (author) / Lin, Xujian (author) / Ji, Tao (author) / Liang, Yongning (author) / Pan, Weijie (author)
2019-09-23
Article (Journal)
Electronic Resource
English
Study on corrosion mechanism of alkali-activated concrete with biogenic sulfuric acid
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