A platform for research: civil engineering, architecture and urbanism
A platform for research: civil engineering, architecture and urbanism
Electric–hydraulic–chemical coupled modeling of solute transport through landfill clay liners
Abstract Pollutant migration in dense clay barriers appears to be strongly influenced by the electric double layer of colloidal surfaces. Osmosis that resulted from chemical potential or electric potential difference across the clay membrane has been successively described in a number of theoretical works. Streaming potential (SP) which is present in charged porous medium under hydraulic gradient has been recognized as a significant factor governing the mass migration in compacted clays. However, few studies have been carried out in geo-environmental area with regard to this physical phenomenon. A coupled model was proposed to account for the effects of electrical, chemical and fluidic fields on solute transport in porous medium in this study. The electrical field deals with both the streaming potential and the externally applied electrical potential. The coupled nonlinear partial differential equations are numerically simulated by finite element method. Both the steady state solution and the time-dependent solution were investigated with the consideration of a series of influential factors. The streaming potential coefficient and the electro-osmotic coefficient were found to control the solute transport process. The potential application of the materials with tendency of producing SP was discussed. With appropriate selection of materials and parameters, optimum barring effect could be obtained for soil barriers in waste containment applications.
Highlights We proposed an electrical–chemo-hydraulic coupled solute transport model. We addressed significant membrane properties present in compacted clay liners. We investigated both the steady state solution and the time-dependent solution. Model was verified by degenerated form of solution and experimental results. Membrane properties (kstr, ke) control the solute transport and permeability.
Electric–hydraulic–chemical coupled modeling of solute transport through landfill clay liners
Abstract Pollutant migration in dense clay barriers appears to be strongly influenced by the electric double layer of colloidal surfaces. Osmosis that resulted from chemical potential or electric potential difference across the clay membrane has been successively described in a number of theoretical works. Streaming potential (SP) which is present in charged porous medium under hydraulic gradient has been recognized as a significant factor governing the mass migration in compacted clays. However, few studies have been carried out in geo-environmental area with regard to this physical phenomenon. A coupled model was proposed to account for the effects of electrical, chemical and fluidic fields on solute transport in porous medium in this study. The electrical field deals with both the streaming potential and the externally applied electrical potential. The coupled nonlinear partial differential equations are numerically simulated by finite element method. Both the steady state solution and the time-dependent solution were investigated with the consideration of a series of influential factors. The streaming potential coefficient and the electro-osmotic coefficient were found to control the solute transport process. The potential application of the materials with tendency of producing SP was discussed. With appropriate selection of materials and parameters, optimum barring effect could be obtained for soil barriers in waste containment applications.
Highlights We proposed an electrical–chemo-hydraulic coupled solute transport model. We addressed significant membrane properties present in compacted clay liners. We investigated both the steady state solution and the time-dependent solution. Model was verified by degenerated form of solution and experimental results. Membrane properties (kstr, ke) control the solute transport and permeability.
Electric–hydraulic–chemical coupled modeling of solute transport through landfill clay liners
Li, Zhenze (author) / Xue, Qiang (author) / Katsumi, Takeshi (author) / Inui, Toru (author)
Applied Clay Science ; 101 ; 541-552
2014-09-16
12 pages
Article (Journal)
Electronic Resource
English
Electric–hydraulic–chemical coupled modeling of solute transport through landfill clay liners
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