Characteristics, sources and evolution processes of atmospheric organic aerosols at a roadside site in Hong Kong: Fid-Bau Portal

Characteristics, sources and evolution processes of atmospheric organic aerosols at a roadside site in Hong Kong

Yao, Dawen / Lyu, Xiaopu / Lu, Haoxian / Zeng, Lewei / Liu, Tengyu / Chan, Chak K. / Guo, Hai

Abstract A sampling campaign was conducted at an urban roadside site in Hong Kong from Nov. to Dec. in 2017 using a suite of state-of-the-art instruments to monitor compositions of non-refractory sub-micron particulate matter (NR-PM1) and gaseous pollutants. Results showed that the average NR-PM1 concentration was 26.1 ± 0.7 μg/m³ (average ± 95% confidence interval) and organic aerosol (OA) contributed the most to NR-PM1 with a proportion of 57.7 ± 0.2%. The aerosol size distributions of bulk composition of NR-PM1 presented a peak at ~600 nm with internal mixtures of the organic and inorganic components, while there were a larger proportion of primary organic particles at < 200 nm, indicating intensive emissions of primary organics at this site. Positive matrix factorization (PMF) analysis was applied to the measurement data and four OA components were identified, including a hydrocarbon-like OA (HOA) factor, a cooking organic aerosol (COA) factor and two oxygenated OA (OOA) factors of different oxidation levels: less oxidized OOA (LO-OOA) and more oxidized OOA (MO-OOA). Strikingly, the contribution of MO-OOA was the highest (30.9 ± 0.4%), suggesting high oxidation degree and/or high regional background in the roadside environment. Moreover, the proportion of COA reached 25.4 ± 0.3% at this roadside site with heavy traffic fleet, which was even higher than the percentage of HOA (p < 0.01). The average ratio of $C_{3} H_{3} O^{+}$ / $C_{3} H_{5} O^{+}$ (2.01 ± 0.01) and the opposite pattern of $C_{3} H_{3} O^{+}$ / $C_{3} H_{5} O^{+}$ to Ox during daytime hours suggested that the COA was oxidized to some extent when transported to the site. The findings implied that cooking activities are a significant source of organic aerosols in Hong Kong, even at a busy road. Control measures should focus on both cooking and traffic emissions in Hong Kong.

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Highlights • The proportion of COA in NR-PM1 was higher than HOA at this traffic-busy site. • The pattern of $C_{3} H_{3} O^{+}$ / $C_{3} H_{5} O^{+}$ ratio was opposite to the trend of Ox during daytime hours. • Cooking activities are a significant source of organic aerosols in Hong Kong.