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Spatial variability of carbon dioxide in the urban canopy layer and implications for flux measurements
Abstract This contribution reports CO2 mixing ratios measured in the urban canopy layer (UCL) of a residential neighborhood in Vancouver, BC, Canada and discusses the relevance of UCL CO2 temporal and spatial variability to local-scale eddy covariance (EC) fluxes measured above the UCL. Measurements were conducted from a mobile vehicle-mounted platform over a continuous, 26-h period in the longterm turbulent flux source area of an urban EC tower. Daytime mixing ratios were highest along arterial roads and largely a function of proximity to vehicle traffic CO2 sources. At night, there was a distinct negative correlation between potential air temperature and CO2 mixing ratios. The spatial distribution of CO2 was controlled by topography and micro-scale advective processes (i.e. cold-air pooling). Mobile CO2 measurements were then used to calculate CO2 storage changes (F S) in the UCL volume and compared to single-layer F S estimates calculated from the EC system. In total, five variations of F S were calculated. On average, the choice of F S calculation method affected net measured hourly emissions (F C) by 5.2%. Analysis of F S using a four-year dataset measured at the EC tower show F S was 2.8% of hourly F C for this site on average. At this urban EC location, F S was relatively minor compared to F C and calculation of F S using a single-layer method was adequate, though F S still represents a potentially large uncertainty during individual hours.
Highlights The micro-scale variability of carbon dioxide was mapped in an urban environment. During day, carbon dioxide was mainly a function of proximity to traffic. At night, the distribution was controlled by accumulation due to cold-air pooling. Hourly changes of carbon dioxide storage in the urban canopy layer were calculated. Changes affected measured eddy covariance fluxes on average by 5%, but up to 123%.
Spatial variability of carbon dioxide in the urban canopy layer and implications for flux measurements
Abstract This contribution reports CO2 mixing ratios measured in the urban canopy layer (UCL) of a residential neighborhood in Vancouver, BC, Canada and discusses the relevance of UCL CO2 temporal and spatial variability to local-scale eddy covariance (EC) fluxes measured above the UCL. Measurements were conducted from a mobile vehicle-mounted platform over a continuous, 26-h period in the longterm turbulent flux source area of an urban EC tower. Daytime mixing ratios were highest along arterial roads and largely a function of proximity to vehicle traffic CO2 sources. At night, there was a distinct negative correlation between potential air temperature and CO2 mixing ratios. The spatial distribution of CO2 was controlled by topography and micro-scale advective processes (i.e. cold-air pooling). Mobile CO2 measurements were then used to calculate CO2 storage changes (F S) in the UCL volume and compared to single-layer F S estimates calculated from the EC system. In total, five variations of F S were calculated. On average, the choice of F S calculation method affected net measured hourly emissions (F C) by 5.2%. Analysis of F S using a four-year dataset measured at the EC tower show F S was 2.8% of hourly F C for this site on average. At this urban EC location, F S was relatively minor compared to F C and calculation of F S using a single-layer method was adequate, though F S still represents a potentially large uncertainty during individual hours.
Highlights The micro-scale variability of carbon dioxide was mapped in an urban environment. During day, carbon dioxide was mainly a function of proximity to traffic. At night, the distribution was controlled by accumulation due to cold-air pooling. Hourly changes of carbon dioxide storage in the urban canopy layer were calculated. Changes affected measured eddy covariance fluxes on average by 5%, but up to 123%.
Spatial variability of carbon dioxide in the urban canopy layer and implications for flux measurements
Crawford, B. (author) / Christen, A. (author)
Atmospheric Environment ; 98 ; 308-322
2014-08-22
15 pages
Article (Journal)
Electronic Resource
English
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