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Structure and micro-nanomechanical characterization of synthetic calcium–silicate–hydrate with Poly(Vinyl Alcohol)
Abstract The principal phase of hardened Portland cement pastes is calcium silicate hydrate (C–S–H), which influences the physical and mechanical properties of construction materials. In this work calcium silicate hydrate (C–S–H) was synthesized, with the addition of Poly(Vinyl Alcohol) (PVA), for the development of C–S–H/polymer nanocomposites. Among the polymers available, PVA is indicated by the literature as one of the most viable for producing C–S–H/polymer complexes. However, no consensus exists regarding the kind of interaction. The resulting compounds were characterized by XRD, FT-IR, TGA, carbon content (CHN), TEM, SEM and elastic modulus and hardness were measured by instrumented indentation. The set of results presented do not confirm the intercalation of PVA in the interlayer space of C–S–H, but presented evidence of the potential for intercalation, since changes in the structure clearly occurred. A significant change in the micro-nanomechanical properties of C–S–H occurred in the presence of PVA.
Structure and micro-nanomechanical characterization of synthetic calcium–silicate–hydrate with Poly(Vinyl Alcohol)
Abstract The principal phase of hardened Portland cement pastes is calcium silicate hydrate (C–S–H), which influences the physical and mechanical properties of construction materials. In this work calcium silicate hydrate (C–S–H) was synthesized, with the addition of Poly(Vinyl Alcohol) (PVA), for the development of C–S–H/polymer nanocomposites. Among the polymers available, PVA is indicated by the literature as one of the most viable for producing C–S–H/polymer complexes. However, no consensus exists regarding the kind of interaction. The resulting compounds were characterized by XRD, FT-IR, TGA, carbon content (CHN), TEM, SEM and elastic modulus and hardness were measured by instrumented indentation. The set of results presented do not confirm the intercalation of PVA in the interlayer space of C–S–H, but presented evidence of the potential for intercalation, since changes in the structure clearly occurred. A significant change in the micro-nanomechanical properties of C–S–H occurred in the presence of PVA.
Structure and micro-nanomechanical characterization of synthetic calcium–silicate–hydrate with Poly(Vinyl Alcohol)
Pelisser, F. (author) / Gleize, P.J.P. (author) / Mikowski, A. (author)
Cement and Concrete Composites ; 48 ; 1-8
2014-01-10
8 pages
Article (Journal)
Electronic Resource
English
Solubility and structure of calcium silicate hydrate
Online Contents | 2004
|Solubility and structure of calcium silicate hydrate
Elsevier | 2004
|Solubility and structure of calcium silicate hydrate
Tema Archive | 2004
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