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Fluorinated alternatives to long-chain perfluoroalkyl carboxylic acids (PFCAs), perfluoroalkane sulfonic acids (PFSAs) and their potential precursors
Abstract Since 2000 there has been an on-going industrial transition to replace long-chain perfluoroalkyl carboxylic acids (PFCAs), perfluoroalkane sulfonic acids (PFSAs) and their precursors. To date, information on these replacements including their chemical identities, however, has not been published or made easily accessible to the public, hampering risk assessment and management of these chemicals. Here we review information on fluorinated alternatives in the public domain. We identify over 20 fluorinated substances that are applied in [i] fluoropolymer manufacture, [ii] surface treatment of textile, leather and carpets, [iii] surface treatment of food contact materials, [iv] metal plating, [v] fire-fighting foams, and [vi] other commercial and consumer products. We summarize current knowledge on their environmental releases, persistence, and exposure of biota and humans. Based on the limited information available, it is unclear whether fluorinated alternatives are safe for humans and the environment. We identify three major data gaps that must be filled to perform meaningful risk assessments and recommend generation of the missing data through cooperation among all stakeholders (industry, regulators, academic scientists and the public).
Highlights Alternatives to long-chain poly- and perfluorinated substances (PFASs) are revealed. Fluorinated alternatives consist of short-chain PFASs and perfluoropolyethers. Information for exposure assessment of fluorinated alternatives is still scarce. Gaps in data needed for risk assessment of fluorinated alternatives are identified.
Fluorinated alternatives to long-chain perfluoroalkyl carboxylic acids (PFCAs), perfluoroalkane sulfonic acids (PFSAs) and their potential precursors
Abstract Since 2000 there has been an on-going industrial transition to replace long-chain perfluoroalkyl carboxylic acids (PFCAs), perfluoroalkane sulfonic acids (PFSAs) and their precursors. To date, information on these replacements including their chemical identities, however, has not been published or made easily accessible to the public, hampering risk assessment and management of these chemicals. Here we review information on fluorinated alternatives in the public domain. We identify over 20 fluorinated substances that are applied in [i] fluoropolymer manufacture, [ii] surface treatment of textile, leather and carpets, [iii] surface treatment of food contact materials, [iv] metal plating, [v] fire-fighting foams, and [vi] other commercial and consumer products. We summarize current knowledge on their environmental releases, persistence, and exposure of biota and humans. Based on the limited information available, it is unclear whether fluorinated alternatives are safe for humans and the environment. We identify three major data gaps that must be filled to perform meaningful risk assessments and recommend generation of the missing data through cooperation among all stakeholders (industry, regulators, academic scientists and the public).
Highlights Alternatives to long-chain poly- and perfluorinated substances (PFASs) are revealed. Fluorinated alternatives consist of short-chain PFASs and perfluoropolyethers. Information for exposure assessment of fluorinated alternatives is still scarce. Gaps in data needed for risk assessment of fluorinated alternatives are identified.
Fluorinated alternatives to long-chain perfluoroalkyl carboxylic acids (PFCAs), perfluoroalkane sulfonic acids (PFSAs) and their potential precursors
Wang, Zhanyun (author) / Cousins, Ian T. (author) / Scheringer, Martin (author) / Hungerbühler, Konrad (author)
Environmental International ; 60 ; 242-248
2013-08-27
7 pages
Article (Journal)
Electronic Resource
English
Temporal trends of PFSAs, PFCAs and selected precursors in Australian serum from 2002 to 2013
Online Contents | 2017
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