A novel approach for preparing exfoliated UV-cured polymer/LDH nanocomposites via pre-exfoliated organic LDH: Fid-Bau Portal

A novel approach for preparing exfoliated UV-cured polymer/LDH nanocomposites via pre-exfoliated organic LDH

Yuan, Yan / Zhang, Yong / Shi, Wenfang

Abstract A novel approach to prepare the exfoliated polymer/layered double hydroxide (LDH) nanocomposites was proposed by synthesizing a pre-exfoliated organic LDH (LDH-SH) firstly, then blended into an acrylic resin, and irradiated by a medium pressure mercury lamp. The LDH-SH was prepared by intercalating LDH with sodium dodecyl sulfate, and then γ-(2,3-epoxypropoxy) propyl trimethoxysilane, followed by grafting with trimethylolpropane thioglycolic acetate. From the X-ray diffraction (XRD) analysis, high resolution scanning electron microscope (HR-SEM) and high resolution transmission electron microscope (HR-TEM) observation, the LDH-SH lost its ordered stacking-structure and was totally pre-exfoliated. After UV irradiation, the formed polymer/LDH nanocomposite possessed the exfoliated microstructure from the transmission electron microscope (TEM) and HR-TEM observations. The dynamic mechanical thermal analyzer (DMTA) results showed that the storage modulus of nanocomposite with 5% LDH-SH loading increased to 44.2MPa from 34.6MPa of the pure polymer, while the tensile strength and persoz hardness were enhanced to 9.3MPa and 107s compared with 8.5MPa and 87s of the pure polymer, respectively.

Graphical abstract Display Omitted Research highlights ► A novel approach for preparing exfoliated polymer/LDH nanocomposites was proposed. ► The approach was via synthesizing a pre-exfoliated hybrid LDH (LDH-SH). ► LDH-SH was applied to a UV curable system forming a totally exfoliated nanocomposite. ► LDH-SH can be used to prepare most kinds of exfoliated polymer/LDH nanocomposites.