A platform for research: civil engineering, architecture and urbanism
A platform for research: civil engineering, architecture and urbanism
Deciphering the influence of superabsorbent polymers on cement hydration and portlandite formation
https://orcid.org/0000-0001-6764-4749
Abstract Superabsorbent polymers (SAPs) have emerged as promising additives to regulate cement hydration via their intrinsic water absorption/desorption characteristics. This paper aims to investigate the influence of SAPs with different functional groups on the development of cement hydration and growth of calcium hydroxide (CH). The current experiment firstly uncovered the active control mechanism of CH in cement paste by SAPs, especially for the nucleation site and crystallization orientation. Specifically, the pores left behind SAPs after water release usually processed higher w/c ratio, Ca2+ concentration and smaller crystallization pressure, which jointly triggered the in-situ nucleation and crystallization of CH along (0 0 1). However, the hydration degree of cement paste was reduced by 0.1∼4.4% with addition of SAPs, especially in the early stage, which was attributed to that less free water can be used for cement hydration due to the strong water absorption property of SAPs. These insights provide a valuable foundation for deploying SAPs in an active control strategy for CH growth position and crystal form in cement-based materials.
Highlights The nucleation site and crystallization orientation of CH can be controlled by SAPs. Higher w/c ratio, Ca2+ concentration triggers the formation of CH around SAPs. The addition of SAPs reduced the hydration degree of cement paste by 0.1 ∼ 4.4%. The addition of SAPs primarily affects hydration during the early stage.
Deciphering the influence of superabsorbent polymers on cement hydration and portlandite formation
https://orcid.org/0000-0001-6764-4749
Abstract Superabsorbent polymers (SAPs) have emerged as promising additives to regulate cement hydration via their intrinsic water absorption/desorption characteristics. This paper aims to investigate the influence of SAPs with different functional groups on the development of cement hydration and growth of calcium hydroxide (CH). The current experiment firstly uncovered the active control mechanism of CH in cement paste by SAPs, especially for the nucleation site and crystallization orientation. Specifically, the pores left behind SAPs after water release usually processed higher w/c ratio, Ca2+ concentration and smaller crystallization pressure, which jointly triggered the in-situ nucleation and crystallization of CH along (0 0 1). However, the hydration degree of cement paste was reduced by 0.1∼4.4% with addition of SAPs, especially in the early stage, which was attributed to that less free water can be used for cement hydration due to the strong water absorption property of SAPs. These insights provide a valuable foundation for deploying SAPs in an active control strategy for CH growth position and crystal form in cement-based materials.
Highlights The nucleation site and crystallization orientation of CH can be controlled by SAPs. Higher w/c ratio, Ca2+ concentration triggers the formation of CH around SAPs. The addition of SAPs reduced the hydration degree of cement paste by 0.1 ∼ 4.4%. The addition of SAPs primarily affects hydration during the early stage.
Deciphering the influence of superabsorbent polymers on cement hydration and portlandite formation
https://orcid.org/0000-0001-6764-4749
Abstract Superabsorbent polymers (SAPs) have emerged as promising additives to regulate cement hydration via their intrinsic water absorption/desorption characteristics. This paper aims to investigate the influence of SAPs with different functional groups on the development of cement hydration and growth of calcium hydroxide (CH). The current experiment firstly uncovered the active control mechanism of CH in cement paste by SAPs, especially for the nucleation site and crystallization orientation. Specifically, the pores left behind SAPs after water release usually processed higher w/c ratio, Ca2+ concentration and smaller crystallization pressure, which jointly triggered the in-situ nucleation and crystallization of CH along (0 0 1). However, the hydration degree of cement paste was reduced by 0.1∼4.4% with addition of SAPs, especially in the early stage, which was attributed to that less free water can be used for cement hydration due to the strong water absorption property of SAPs. These insights provide a valuable foundation for deploying SAPs in an active control strategy for CH growth position and crystal form in cement-based materials.
Highlights The nucleation site and crystallization orientation of CH can be controlled by SAPs. Higher w/c ratio, Ca2+ concentration triggers the formation of CH around SAPs. The addition of SAPs reduced the hydration degree of cement paste by 0.1 ∼ 4.4%. The addition of SAPs primarily affects hydration during the early stage.
Deciphering the influence of superabsorbent polymers on cement hydration and portlandite formation
Wang, Han (author) / Liu, Zhiyong (author) / Wang, Fengjuan (author) / Zhang, Jiawen (author) / Guo, Le (author) / Zhang, Yu (author) / Li, Yali (author) / Lin, Junlin (author) / Lu, Zeyu (author) / Jiang, Jinyang (author)
2024-02-12
Article (Journal)
Electronic Resource
English
Nucleation of Portlandite Clusters in Cement Paste at Very Early Stage of Hydration
| British Library Online Contents | 2010