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Effect of blast furnace slag on self-healing of microcracks in cementitious materials
Abstract The physico-chemical process of self-healing in blast furnace slag cement paste was investigated in this paper. With a high slag content i.e., 66% in cement paste and saturated Ca(OH)2 solution as activator, it was found that the reaction products formed in cracks are composed of CSH, ettringite, hydrogarnet and OH–hydrotalcite. The fraction of CSH in the reaction products is much larger than the other minerals. Large amount of ettringite formed in cracks indicates the leaching of SO4 2− ions from the bulk paste and consequently the recrystallization. Self-healing proceeds fast within 50h and then slows down. According to thermodynamic modeling, when the newly formed reaction products are carbonated, the filling fraction of crack increases first and then decreases. Low soluble minerals such as silica gel, gibbsite and calcite are formed. Compared to Portland cement paste, the potential of self-healing in slag cement paste is higher when the percentage of slag is high.
Highlights Self-healing reaction products in slag cement paste were characterized. Self-healing reaction products formed in time were quantified with image analysis. Self-healing in slag cement paste was simulated with a reactive transport model. Effect of carbonation on self-healing was investigated by thermodynamic modeling. Effect of slag on self-healing was discussed based on experiments and simulation.
Effect of blast furnace slag on self-healing of microcracks in cementitious materials
Abstract The physico-chemical process of self-healing in blast furnace slag cement paste was investigated in this paper. With a high slag content i.e., 66% in cement paste and saturated Ca(OH)2 solution as activator, it was found that the reaction products formed in cracks are composed of CSH, ettringite, hydrogarnet and OH–hydrotalcite. The fraction of CSH in the reaction products is much larger than the other minerals. Large amount of ettringite formed in cracks indicates the leaching of SO4 2− ions from the bulk paste and consequently the recrystallization. Self-healing proceeds fast within 50h and then slows down. According to thermodynamic modeling, when the newly formed reaction products are carbonated, the filling fraction of crack increases first and then decreases. Low soluble minerals such as silica gel, gibbsite and calcite are formed. Compared to Portland cement paste, the potential of self-healing in slag cement paste is higher when the percentage of slag is high.
Highlights Self-healing reaction products in slag cement paste were characterized. Self-healing reaction products formed in time were quantified with image analysis. Self-healing in slag cement paste was simulated with a reactive transport model. Effect of carbonation on self-healing was investigated by thermodynamic modeling. Effect of slag on self-healing was discussed based on experiments and simulation.
Effect of blast furnace slag on self-healing of microcracks in cementitious materials
Huang, Haoliang (author) / Ye, Guang (author) / Damidot, Denis (author)
Cement and Concrete Research ; 60 ; 68-82
2014-03-21
15 pages
Article (Journal)
Electronic Resource
English
Effect of blast furnace slag on self-healing of microcracks in cementitious materials
| Online Contents | 2014
Effect of blast furnace slag on self-healing of microcracks in cementitious materials
| British Library Online Contents | 2014
Effect of blast furnace slag on self-healing of microcracks in cementitious materials
| Tema Archive | 2014
| British Library Online Contents | 2016