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Surfactant-free emulsion polymerization of styrene in the presence of silylated montmorillonite

Ianchis, R. / Donescu, D. / Petcu, C. / Ghiurea, M. / Anghel, D.F. / Stanga, G. / Marcu, A.

AbstractWe report surfactant-free emulsion polymerization of styrene by using five types of montmorillonite modified by grafting monofunctional alkoxysilanes. Dynamic light scattering (DLS) determinations were strongly influenced by the presence of modified montmorillonite. FTIR and XRD spectra confirmed the incorporation of montmorillonite in the polymer matrix. The morphology of the latex particles was changed. Spherical and snowman particles indicated that the platelets were both inside and outside of the polymer particles.

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Surfactant-free emulsion polymerization of styrene in the presence of silylated montmorillonite

Ianchis, R. / Donescu, D. / Petcu, C. / Ghiurea, M. / Anghel, D.F. / Stanga, G. / Marcu, A.

AbstractWe report surfactant-free emulsion polymerization of styrene by using five types of montmorillonite modified by grafting monofunctional alkoxysilanes. Dynamic light scattering (DLS) determinations were strongly influenced by the presence of modified montmorillonite. FTIR and XRD spectra confirmed the incorporation of montmorillonite in the polymer matrix. The morphology of the latex particles was changed. Spherical and snowman particles indicated that the platelets were both inside and outside of the polymer particles.

Surfactant-free emulsion polymerization of styrene in the presence of silylated montmorillonite

Ianchis, R. / Donescu, D. / Petcu, C. / Ghiurea, M. / Anghel, D.F. / Stanga, G. / Marcu, A.

AbstractWe report surfactant-free emulsion polymerization of styrene by using five types of montmorillonite modified by grafting monofunctional alkoxysilanes. Dynamic light scattering (DLS) determinations were strongly influenced by the presence of modified montmorillonite. FTIR and XRD spectra confirmed the incorporation of montmorillonite in the polymer matrix. The morphology of the latex particles was changed. Spherical and snowman particles indicated that the platelets were both inside and outside of the polymer particles.

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Title:

Surfactant-free emulsion polymerization of styrene in the presence of silylated montmorillonite

Contributors:

Ianchis, R. (author) / Donescu, D. (author) / Petcu, C. (author) / Ghiurea, M. (author) / Anghel, D.F. (author) / Stanga, G. (author) / Marcu, A. (author)

Published in:

Applied Clay Science ; 45 ; 164-170

Publication date:

2009-04-19

Size:

7 pages

ISSN:

DOI:

https://doi.org/10.1016/j.clay.2009.04.012

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Montmorillonite , Surfactant-free emulsion polymerization , Polystyrene , Latex

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