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Solubility of ammonia in liquid water and generation of trace levels of standard gaseous ammonia
Abstract Equilibrium gas phase concentration of ammonia in dilute solution has been measured as a function of total ammonia + ammonium concentration (0.002–0.10 M), pH (6–10) and temperature (278.8−290.6 K). Henry's Law is obeyed under these conditions and may be expressed as In K H(M atm−1) = 4092/T −9.70 with a relative standard error of less than 5 %, in good agreement with NBS thermodynamic data. Convenient generation of trace levels of ammonia (1.33 × 10−8–7.77 × 10−4 atm) using a porous membrane tube is described.
Solubility of ammonia in liquid water and generation of trace levels of standard gaseous ammonia
Abstract Equilibrium gas phase concentration of ammonia in dilute solution has been measured as a function of total ammonia + ammonium concentration (0.002–0.10 M), pH (6–10) and temperature (278.8−290.6 K). Henry's Law is obeyed under these conditions and may be expressed as In K H(M atm−1) = 4092/T −9.70 with a relative standard error of less than 5 %, in good agreement with NBS thermodynamic data. Convenient generation of trace levels of ammonia (1.33 × 10−8–7.77 × 10−4 atm) using a porous membrane tube is described.
Solubility of ammonia in liquid water and generation of trace levels of standard gaseous ammonia
Dasgupta, Purnendu K. (author) / Dong, Shen (author)
Atmospheric Environment ; 20 ; 565-570
1985-08-02
6 pages
Article (Journal)
Electronic Resource
English
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