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Low-temperature sintered lead-free microwave dielectric ceramic and preparation method thereof
The invention provides low-temperature sintered lead-free microwave dielectric ceramic and a preparation method thereof. By adopting the method, continuous adjustable dielectric constant is realized by regulating the Mg/Ca ratio of [Cax, Mg(1-x)]TiO3 powder which serves as a base material; low-temperature sintering of the ceramic material at 800-900 DEG C is realized by adding CaO-Al2O3-B2O3-SiO2 microcrystalline glass. The method comprises the following steps: firstly, synthesizing [Cax, Mg(1-x)]TiO3 ceramic powder, and synthesizing CaO-Al2O3-B2O3-SiO2 microcrystalline glass; then, performing ball-milling, dosing, tape-casting, molding and batching out, sintering and annealing to obtain a low-consumption multi-layer ceramic dielectric material with excellent performance. According to the method, the microcrystalline glass/ceramic green-compact is molded by adopting thick film tape-casting, and multiple layers of the green compact are laminated and subjected to low-temperature sintering to prepare a ceramic substrate, so that the dielectric loss can be reduced, the dielectric constant is adjustable in a range of 9-35, tan delta is less than 0.0002 under 10MHz, and tan delta is less than 0.0015 under 1-10GHz; low-temperature sintering is realized, and industrial production can be realized by combining with an Ag-Pd electrode.
Low-temperature sintered lead-free microwave dielectric ceramic and preparation method thereof
The invention provides low-temperature sintered lead-free microwave dielectric ceramic and a preparation method thereof. By adopting the method, continuous adjustable dielectric constant is realized by regulating the Mg/Ca ratio of [Cax, Mg(1-x)]TiO3 powder which serves as a base material; low-temperature sintering of the ceramic material at 800-900 DEG C is realized by adding CaO-Al2O3-B2O3-SiO2 microcrystalline glass. The method comprises the following steps: firstly, synthesizing [Cax, Mg(1-x)]TiO3 ceramic powder, and synthesizing CaO-Al2O3-B2O3-SiO2 microcrystalline glass; then, performing ball-milling, dosing, tape-casting, molding and batching out, sintering and annealing to obtain a low-consumption multi-layer ceramic dielectric material with excellent performance. According to the method, the microcrystalline glass/ceramic green-compact is molded by adopting thick film tape-casting, and multiple layers of the green compact are laminated and subjected to low-temperature sintering to prepare a ceramic substrate, so that the dielectric loss can be reduced, the dielectric constant is adjustable in a range of 9-35, tan delta is less than 0.0002 under 10MHz, and tan delta is less than 0.0015 under 1-10GHz; low-temperature sintering is realized, and industrial production can be realized by combining with an Ag-Pd electrode.
Low-temperature sintered lead-free microwave dielectric ceramic and preparation method thereof
LIU MING (author) / XU XIAOYING (author) / LI JILI (author) / SHI DONGMEI (author) / JIA TIEKUN (author) / ZHAO YINGGANG (author) / LIU JIN (author)
2015-07-15
Patent
Electronic Resource
English
IPC:
C04B
Kalk
,
LIME
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