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A platform for research: civil engineering, architecture and urbanism
Preparation method of naphthalene-series water reducing agent
The invention relates to a preparation method of a naphthalene-series water reducing agent. The method comprises the following steps: (1) methylnaphthalene and phenol are separately sulfonated, such that a sulfonated methylnaphthalene material and a p-hydroxybenzenesulfonic acid material are obtained; (2) the sulfonated methylnaphthalene material is subjected to a hydrolysis reaction; un-reacted methylnaphthalene or homologs thereof are removed through zeotropy; the rest of the sulfonated methylnaphthalene material enters a reaction in the step (3); (3) the sulfonated methylnaphthalene material obtained in the step (2) and the p-hydroxybenzenesulfonic acid material obtained in the step (1) are subjected to a condensation reaction with formaldehyde acidified with concentrated sulfuric acid, such that a condensed material is obtained; and (4) alkali liquid is added into the condensed material obtained in the step (3), such that a neutralization reaction is carried out, until the pH value is 7.5-9; and the naphthalene-series water reducing agent is obtained when the reaction is finished. The naphthalene-series water reducing agent provided by the invention has the excellent performances of good adaptability to cement, good concrete workability, high plasticity-maintaining performance, low concrete gradual loss, high water reducing rate, and the like. The preparation method has the advantages of simple process and easy-to-control reaction conditions. With the method, naphthalene-series water reducing agent production cost can be reduced.
Preparation method of naphthalene-series water reducing agent
The invention relates to a preparation method of a naphthalene-series water reducing agent. The method comprises the following steps: (1) methylnaphthalene and phenol are separately sulfonated, such that a sulfonated methylnaphthalene material and a p-hydroxybenzenesulfonic acid material are obtained; (2) the sulfonated methylnaphthalene material is subjected to a hydrolysis reaction; un-reacted methylnaphthalene or homologs thereof are removed through zeotropy; the rest of the sulfonated methylnaphthalene material enters a reaction in the step (3); (3) the sulfonated methylnaphthalene material obtained in the step (2) and the p-hydroxybenzenesulfonic acid material obtained in the step (1) are subjected to a condensation reaction with formaldehyde acidified with concentrated sulfuric acid, such that a condensed material is obtained; and (4) alkali liquid is added into the condensed material obtained in the step (3), such that a neutralization reaction is carried out, until the pH value is 7.5-9; and the naphthalene-series water reducing agent is obtained when the reaction is finished. The naphthalene-series water reducing agent provided by the invention has the excellent performances of good adaptability to cement, good concrete workability, high plasticity-maintaining performance, low concrete gradual loss, high water reducing rate, and the like. The preparation method has the advantages of simple process and easy-to-control reaction conditions. With the method, naphthalene-series water reducing agent production cost can be reduced.
Preparation method of naphthalene-series water reducing agent
LI YINGBIN (author) / JIN RUIHAO (author) / YAN JIANGMIN (author) / HAN YULONG (author) / LYU PING (author)
2016-01-13
Patent
Electronic Resource
English
IPC:
C04B
Kalk
,
LIME
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