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Prussian blue and Prussian blue analogue nanosheet film materials and in-situ preparation method thereof
The invention discloses Prussian blue and Prussian blue analogue nanosheet film materials and an in-situ preparation method thereof. A substrate is modified with two high-molecular polymers with opposite charges, namely PAH (poly allylamine hydrochloride) and PSS (sodium polystyrene sulfonate), and Prussian blue or Prussian blue analogue square nanosheets are synthesized in situ on the modified substrate with metal ionic salt and potassium ferrocyanide as raw materials. A test of a prepared nanosheet film through ultraviolet-visible spectroscopy, a scanning electron microscope and a transmission electron microscope proves that the nanosheets have controllable size and are uniformly dispersed. The growth direction of the nanosheets is limited by the porous network of the high-molecular polymers, so that the nanosheets are square or rectangular, water is used as a solvent in the whole preparation process of the film and is harmless to the environment, the preparation process is simple and feasible, the cost is low, equipment is simple, the film materials with different kinds of functionality are obtained by changing the variety of simple ions, and the in-situ preparation method has important application value in the field of material preparation.
Prussian blue and Prussian blue analogue nanosheet film materials and in-situ preparation method thereof
The invention discloses Prussian blue and Prussian blue analogue nanosheet film materials and an in-situ preparation method thereof. A substrate is modified with two high-molecular polymers with opposite charges, namely PAH (poly allylamine hydrochloride) and PSS (sodium polystyrene sulfonate), and Prussian blue or Prussian blue analogue square nanosheets are synthesized in situ on the modified substrate with metal ionic salt and potassium ferrocyanide as raw materials. A test of a prepared nanosheet film through ultraviolet-visible spectroscopy, a scanning electron microscope and a transmission electron microscope proves that the nanosheets have controllable size and are uniformly dispersed. The growth direction of the nanosheets is limited by the porous network of the high-molecular polymers, so that the nanosheets are square or rectangular, water is used as a solvent in the whole preparation process of the film and is harmless to the environment, the preparation process is simple and feasible, the cost is low, equipment is simple, the film materials with different kinds of functionality are obtained by changing the variety of simple ions, and the in-situ preparation method has important application value in the field of material preparation.
Prussian blue and Prussian blue analogue nanosheet film materials and in-situ preparation method thereof
WANG JINMIN (author) / LAN YANG (author)
2016-01-27
Patent
Electronic Resource
English
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