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Paste formula for improving binding force between metallization and ceramic
The invention discloses a paste formula for improving binding force between metallization and ceramic, and belongs to the technical field of ceramic metallization. The ceramic metallization paste comprises the following raw materials in percentage by mass: 12.5%-15.5% of manganese powder, 5.4%-8.2% of low-temperature molten oxide, 0.4%-0.7% of strontium sulfate, 14.0%-16.8% of a binder and the balance of molybdenum powder. The low-temperature molten oxide comprises the following components in percentage by mass: 84%-89% of aluminum oxide, 10.5%-15% of silicon dioxide, 0.3%-0.6% of calcium oxide and 0.1%-0.4% of montmorillonite. The traditional ceramic metallization molybdenum-manganese paste formula is optimized, the novel molybdenum-manganese paste is prepared by increasing the manganese content, reducing the low-temperature molten oxide content and then adding strontium sulfate microspheres, the novel molybdenum-manganese paste is applied to welding of 95% aluminum oxide ceramic and metal, the welding performance is remarkably improved, the thickness of the obtained metallization coating is 8-40 microns, the thickness of the nickel layer is 1-5 microns, and the metallization tensile strength is not lower than 175 MPa, and the application range is wide.
本发明公开了一种提高金属化与陶瓷结合力的膏剂配方,属于陶瓷金属化技术领域。该陶瓷金属化膏剂按质量百分数包括以下原料:锰粉12.5%‑15.5%,低温熔融氧化物5.4%‑8.2%,硫酸锶0.4%‑0.7%,粘结剂14.0%‑16.8%,余量为钼粉。其中,低温熔融氧化物按质量百分数包括:氧化铝84%‑89%、二氧化硅10.5%‑15%、氧化钙0.3%‑0.6%、蒙脱土0.1%‑0.4%。本发明优化了传统陶瓷金属化钼锰膏剂配方,通过提高锰含量降低低温熔融氧化物含量、再加入硫酸锶微球制得一种新的钼锰膏剂,将其应用于95%氧化铝陶瓷与金属的焊接,焊接性能显著提高,所得金属化涂层厚度为8‑40μm,镍层厚度为1‑5μm,金属化抗拉强度不低于175MPa,应用广泛。
Paste formula for improving binding force between metallization and ceramic
The invention discloses a paste formula for improving binding force between metallization and ceramic, and belongs to the technical field of ceramic metallization. The ceramic metallization paste comprises the following raw materials in percentage by mass: 12.5%-15.5% of manganese powder, 5.4%-8.2% of low-temperature molten oxide, 0.4%-0.7% of strontium sulfate, 14.0%-16.8% of a binder and the balance of molybdenum powder. The low-temperature molten oxide comprises the following components in percentage by mass: 84%-89% of aluminum oxide, 10.5%-15% of silicon dioxide, 0.3%-0.6% of calcium oxide and 0.1%-0.4% of montmorillonite. The traditional ceramic metallization molybdenum-manganese paste formula is optimized, the novel molybdenum-manganese paste is prepared by increasing the manganese content, reducing the low-temperature molten oxide content and then adding strontium sulfate microspheres, the novel molybdenum-manganese paste is applied to welding of 95% aluminum oxide ceramic and metal, the welding performance is remarkably improved, the thickness of the obtained metallization coating is 8-40 microns, the thickness of the nickel layer is 1-5 microns, and the metallization tensile strength is not lower than 175 MPa, and the application range is wide.
本发明公开了一种提高金属化与陶瓷结合力的膏剂配方,属于陶瓷金属化技术领域。该陶瓷金属化膏剂按质量百分数包括以下原料:锰粉12.5%‑15.5%,低温熔融氧化物5.4%‑8.2%,硫酸锶0.4%‑0.7%,粘结剂14.0%‑16.8%,余量为钼粉。其中,低温熔融氧化物按质量百分数包括:氧化铝84%‑89%、二氧化硅10.5%‑15%、氧化钙0.3%‑0.6%、蒙脱土0.1%‑0.4%。本发明优化了传统陶瓷金属化钼锰膏剂配方,通过提高锰含量降低低温熔融氧化物含量、再加入硫酸锶微球制得一种新的钼锰膏剂,将其应用于95%氧化铝陶瓷与金属的焊接,焊接性能显著提高,所得金属化涂层厚度为8‑40μm,镍层厚度为1‑5μm,金属化抗拉强度不低于175MPa,应用广泛。
Paste formula for improving binding force between metallization and ceramic
一种提高金属化与陶瓷结合力的膏剂配方
CHEN GUIBAO (author) / LIU ZAN (author) / XU XIAOYANG (author)
2021-11-02
Patent
Electronic Resource
Chinese
IPC:
C04B
Kalk
,
LIME
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