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Preparation method and application of macroscopic gradient pore structure porous ceramic with Thiessen polygon characteristics
The invention relates to the field of porous materials, in particular to a preparation method and application of macroscopic gradient pore structure porous ceramic with Thiessen polygon characteristics. The method comprises the following steps: constructing geometric figures with different aperture sizes and gradient transition in a space based on a Thiessen polygon principle by utilizing three-dimensional modeling software; forming a resin template with a macroscopic gradient pore structure through photocuring 3D printing; preparing ceramic slurry, and carrying out ball milling and uniform mixing; injecting the ceramic slurry into the mold in which the resin template is placed, degassing, compacting and curing to obtain a porous ceramic green body; and carrying out pyrolysis on the green body to remove the resin template, degreasing, sintering at high temperature and the like to realize densification, thereby obtaining the porous ceramic with the macroscopic gradient pore structure. The porous ceramic has a cascade transition random pore structure, a wide volume fraction range, good geometric dimension precision and high density, efficient preparation of the macroscopic gradient pore structure porous ceramic with Thiessen polygon characteristics is achieved, and a foundation is laid for application of the porous ceramic.
本发明涉及多孔材料领域,一种具有泰森多边形特征的宏观梯度孔结构多孔陶瓷制备方法及应用。利用三维建模软件,基于泰森多边形原理构建出在空间内具备不同孔径尺寸且成梯度过渡的几何图形;光固化3D打印成型具有宏观梯度孔结构的树脂模板;配制陶瓷浆料,并球磨混合均匀;向放置好树脂模板的模具内注入陶瓷浆料,除气、振实、固化得到多孔陶瓷坯体;坯体经热解去除树脂模板、脱脂、高温烧结等工艺实现致密化,得到具有宏观梯度孔结构的多孔陶瓷。该多孔陶瓷具有成梯级过渡的随机孔隙结构、较宽的体积分数范围、良好的几何尺寸精度、较高的致密度,实现了具有泰森多边形特征的宏观梯度孔结构多孔陶瓷制备高效制备,为其应用奠定基础。
Preparation method and application of macroscopic gradient pore structure porous ceramic with Thiessen polygon characteristics
The invention relates to the field of porous materials, in particular to a preparation method and application of macroscopic gradient pore structure porous ceramic with Thiessen polygon characteristics. The method comprises the following steps: constructing geometric figures with different aperture sizes and gradient transition in a space based on a Thiessen polygon principle by utilizing three-dimensional modeling software; forming a resin template with a macroscopic gradient pore structure through photocuring 3D printing; preparing ceramic slurry, and carrying out ball milling and uniform mixing; injecting the ceramic slurry into the mold in which the resin template is placed, degassing, compacting and curing to obtain a porous ceramic green body; and carrying out pyrolysis on the green body to remove the resin template, degreasing, sintering at high temperature and the like to realize densification, thereby obtaining the porous ceramic with the macroscopic gradient pore structure. The porous ceramic has a cascade transition random pore structure, a wide volume fraction range, good geometric dimension precision and high density, efficient preparation of the macroscopic gradient pore structure porous ceramic with Thiessen polygon characteristics is achieved, and a foundation is laid for application of the porous ceramic.
本发明涉及多孔材料领域,一种具有泰森多边形特征的宏观梯度孔结构多孔陶瓷制备方法及应用。利用三维建模软件,基于泰森多边形原理构建出在空间内具备不同孔径尺寸且成梯度过渡的几何图形;光固化3D打印成型具有宏观梯度孔结构的树脂模板;配制陶瓷浆料,并球磨混合均匀;向放置好树脂模板的模具内注入陶瓷浆料,除气、振实、固化得到多孔陶瓷坯体;坯体经热解去除树脂模板、脱脂、高温烧结等工艺实现致密化,得到具有宏观梯度孔结构的多孔陶瓷。该多孔陶瓷具有成梯级过渡的随机孔隙结构、较宽的体积分数范围、良好的几何尺寸精度、较高的致密度,实现了具有泰森多边形特征的宏观梯度孔结构多孔陶瓷制备高效制备,为其应用奠定基础。
Preparation method and application of macroscopic gradient pore structure porous ceramic with Thiessen polygon characteristics
一种具有泰森多边形特征的宏观梯度孔结构多孔陶瓷制备方法及应用
ZHANG JINGSONG (author) / XU YICHEN (author) / GAO YONG (author) / YANG ZHENMING (author) / TIAN CHONG (author)
2023-03-03
Patent
Electronic Resource
Chinese
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