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Proton conductor electrolytic cell composite membrane, membrane electrode and preparation method
The invention discloses a proton conductor electrolytic cell composite membrane, a membrane electrode and a preparation method, and belongs to the field of fuel cells and electrolytic cells. The composite membrane consists of a proton conductor-based electrolyte layer, a zirconium oxide-based electrolyte membrane layer and a cerium oxide-based electrolyte membrane layer which are tightly connected in sequence, the proton conductor-based electrolyte layer is made of BaZr1-zNzO3, and z is greater than or equal to 0.01 and less than 1; the material of the zirconia-based electrolyte membrane layer is MyZr1-yO2, wherein y is more than or equal to 0.01 and less than or equal to 0.5; the material of the cerium oxide-based electrolyte membrane layer is LnxCe1-xO2, wherein x is greater than or equal to 0.01 and less than or equal to 0.5. The composite membrane-based electrolytic tank has very low proton transmission resistance and relatively large electron blocking resistance, and shows excellent electrolytic performance at 400-600 DEG C.
本发明公开了一种质子导体电解池复合膜、膜电极及制备方法，属于燃料电池及电解池领域。该复合膜由依次紧密连接的质子导体基电解质层、氧化锆基电解质膜层和氧化铈基电解质膜层组成；质子导体基电解质层的材料为BaZr1‑zNzO3，0.01≤z＜1；氧化锆基电解质膜层的材料为MyZr1‑yO2，0.01≤y≤0.5；氧化铈基电解质膜层的材料为LnxCe1‑xO2，0.01≤x≤0.5。该复合膜基电解池具有非常低的质子传输电阻和较大的电子阻挡电阻，在400～600℃显示出优异的电解性能。
Proton conductor electrolytic cell composite membrane, membrane electrode and preparation method
The invention discloses a proton conductor electrolytic cell composite membrane, a membrane electrode and a preparation method, and belongs to the field of fuel cells and electrolytic cells. The composite membrane consists of a proton conductor-based electrolyte layer, a zirconium oxide-based electrolyte membrane layer and a cerium oxide-based electrolyte membrane layer which are tightly connected in sequence, the proton conductor-based electrolyte layer is made of BaZr1-zNzO3, and z is greater than or equal to 0.01 and less than 1; the material of the zirconia-based electrolyte membrane layer is MyZr1-yO2, wherein y is more than or equal to 0.01 and less than or equal to 0.5; the material of the cerium oxide-based electrolyte membrane layer is LnxCe1-xO2, wherein x is greater than or equal to 0.01 and less than or equal to 0.5. The composite membrane-based electrolytic tank has very low proton transmission resistance and relatively large electron blocking resistance, and shows excellent electrolytic performance at 400-600 DEG C.
本发明公开了一种质子导体电解池复合膜、膜电极及制备方法，属于燃料电池及电解池领域。该复合膜由依次紧密连接的质子导体基电解质层、氧化锆基电解质膜层和氧化铈基电解质膜层组成；质子导体基电解质层的材料为BaZr1‑zNzO3，0.01≤z＜1；氧化锆基电解质膜层的材料为MyZr1‑yO2，0.01≤y≤0.5；氧化铈基电解质膜层的材料为LnxCe1‑xO2，0.01≤x≤0.5。该复合膜基电解池具有非常低的质子传输电阻和较大的电子阻挡电阻，在400～600℃显示出优异的电解性能。
Proton conductor electrolytic cell composite membrane, membrane electrode and preparation method
一种质子导体电解池复合膜、膜电极及制备方法
ZHAO ZHE (author) / SHAO ZHIGANG (author) / CHENG MOJIE (author)
2024-01-02
Patent
Electronic Resource
Chinese
IPC:
C04B
Kalk
,
LIME
| European Patent Office | 2024
| European Patent Office | 2022
| European Patent Office | 2021