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Wall cloth for purifying formaldehyde and preparation method thereof
The invention discloses wall cloth for purifying formaldehyde and a preparation method of the wall cloth, and relates to the field of home decoration. The prepared wall cloth for purifying formaldehyde comprises the composite nanofiber membrane and the phosphorus-nitrogen flame-retardant fiber fabric, thiourea, titanium carbide and triphenylphosphine are calcined to obtain modified carbon nitride, and the photocatalytic performance is improved; by introducing triphenylphosphine, the crystal structure of carbon nitride is reserved, and the photocatalytic performance of carbon nitride is improved through the synergistic effect of triphenylphosphine and titanium dioxide quantum dots; under the excitation of visible light, carbon-hydrogen bonds in formaldehyde are oxidized, and formaldehyde is decomposed into harmless substances; the preparation method comprises the following steps: carrying out addition on amino of trihydroxymethyl aminomethane and a carbon-nitrogen triple bond of dicyandiamide to generate a biguanide structure, adding phosphorus pentoxide for esterification, adding urea, and carrying out acid-base neutralization to prepare a phosphorus-nitrogen flame retardant; the flame retardant is decomposed into phosphoric acid at high temperature, so that the speed of dehydrating and charring on the surface of the fiber can be increased, a compact carbon layer is quickly generated, and a fire source and combustible materials are isolated.
本发明公开了一种净化甲醛的墙布及其制备方法,涉及家居装修领域。本发明制备的净化甲醛的墙布,包括复合纳米纤维膜和磷氮阻燃纤维面料,硫脲、碳化钛和三苯基膦煅烧得改性氮化碳,提高光催化性能;三苯基膦的引入保留了氮化碳的晶体结构,与二氧化钛量子点协同作用改善了氮化碳的光催化性能;在可见光激发下,氧化甲醛中的碳氢键,将甲醛分解为无害物质;三羟甲基氨基甲烷的氨基和双氰胺的碳氮三键加成生成双胍结构,加入五氧化二磷酯化,加入尿素,通过酸碱中和制备磷氮系阻燃剂;阻燃剂在高温下分解成磷酸,能加快纤维表面脱水成炭的速度,迅速生成致密炭层,隔离火源和可燃物。
Wall cloth for purifying formaldehyde and preparation method thereof
The invention discloses wall cloth for purifying formaldehyde and a preparation method of the wall cloth, and relates to the field of home decoration. The prepared wall cloth for purifying formaldehyde comprises the composite nanofiber membrane and the phosphorus-nitrogen flame-retardant fiber fabric, thiourea, titanium carbide and triphenylphosphine are calcined to obtain modified carbon nitride, and the photocatalytic performance is improved; by introducing triphenylphosphine, the crystal structure of carbon nitride is reserved, and the photocatalytic performance of carbon nitride is improved through the synergistic effect of triphenylphosphine and titanium dioxide quantum dots; under the excitation of visible light, carbon-hydrogen bonds in formaldehyde are oxidized, and formaldehyde is decomposed into harmless substances; the preparation method comprises the following steps: carrying out addition on amino of trihydroxymethyl aminomethane and a carbon-nitrogen triple bond of dicyandiamide to generate a biguanide structure, adding phosphorus pentoxide for esterification, adding urea, and carrying out acid-base neutralization to prepare a phosphorus-nitrogen flame retardant; the flame retardant is decomposed into phosphoric acid at high temperature, so that the speed of dehydrating and charring on the surface of the fiber can be increased, a compact carbon layer is quickly generated, and a fire source and combustible materials are isolated.
本发明公开了一种净化甲醛的墙布及其制备方法,涉及家居装修领域。本发明制备的净化甲醛的墙布,包括复合纳米纤维膜和磷氮阻燃纤维面料,硫脲、碳化钛和三苯基膦煅烧得改性氮化碳,提高光催化性能;三苯基膦的引入保留了氮化碳的晶体结构,与二氧化钛量子点协同作用改善了氮化碳的光催化性能;在可见光激发下,氧化甲醛中的碳氢键,将甲醛分解为无害物质;三羟甲基氨基甲烷的氨基和双氰胺的碳氮三键加成生成双胍结构,加入五氧化二磷酯化,加入尿素,通过酸碱中和制备磷氮系阻燃剂;阻燃剂在高温下分解成磷酸,能加快纤维表面脱水成炭的速度,迅速生成致密炭层,隔离火源和可燃物。
Wall cloth for purifying formaldehyde and preparation method thereof
一种净化甲醛的墙布及其制备方法
2024-12-17
Patent
Electronic Resource
Chinese
IPC:
B32B
LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
,
Schichtkörper, d.h. aus Ebenen oder gewölbten Schichten, z.B. mit zell- oder wabenförmiger Form, aufgebaute Erzeugnisse
/
D03D
WOVEN FABRICS
,
Gewebe
/
D04H
Herstellen von flächigem Textilgut, z.B. aus Fasern oder fadenförmigem Material
,
MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL
/
D06B
Behandlung von Textilgut mit Flüssigkeiten, Gasen oder Dämpfen
,
TREATING TEXTILE MATERIALS BY LIQUIDS, GASES, OR VAPOURS
/
D06M
Behandeln von Fasern, Fäden, Garnen, Textilgut, Federn oder aus solchen Materialien hergestelltem Fasergut, soweit nicht anderweitig in Klasse D06 vorgesehen
,
TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
/
E04F
FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
,
Ausbau von Bauwerken, z.B. Treppen, Fußböden
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