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METHODS OF IDENTIFYING A CERAMIC MATERIAL EXHIBITING AN ELECTRIC FIELD INDUCED STRAIN DERIVED FROM A REVERSIBLE PHASE TRANSITION, METHODS OF PREPARATION AND CERAMIC MATERIALS OBTAINABLE THEREFROM
The present invention relates to a method for identifying a solid solution ceramic material of a plurality of perovskite compounds which exhibits an electric field induced strain derived from a reversible phase transition, as well as a method for making such ceramic materials and ceramic materials obtainable therefrom. In particular, the present invention is directed to a method of identifying a solid solution ceramic material of at least three perovskite compounds which exhibits an electric field induced strain derived from a reversible phase transition; said method comprising the steps of: i) determining a molar ratio of at least one tetragonal perovskite compound to at least one non-tetragonal perovskite compound which, when combined to form a solid solution, provides a ceramic material comprising a major portion of a tetragonal phase having an axial ratio c/a of greater than 1.005 to 1.04; and ii) determining a molar ratio of at least one additional non-tetragonal perovskite compound to the combination of perovskite compounds from step i) at the determined molar ratio which, when combined to form a solid solution, provides a ceramic material comprising a major portion of a pseudo-cubic phase having an axial ratio c/a of from 0.995 to 1.005 and/or a rhombohedral angle of 90±0.5 degrees.
METHODS OF IDENTIFYING A CERAMIC MATERIAL EXHIBITING AN ELECTRIC FIELD INDUCED STRAIN DERIVED FROM A REVERSIBLE PHASE TRANSITION, METHODS OF PREPARATION AND CERAMIC MATERIALS OBTAINABLE THEREFROM
The present invention relates to a method for identifying a solid solution ceramic material of a plurality of perovskite compounds which exhibits an electric field induced strain derived from a reversible phase transition, as well as a method for making such ceramic materials and ceramic materials obtainable therefrom. In particular, the present invention is directed to a method of identifying a solid solution ceramic material of at least three perovskite compounds which exhibits an electric field induced strain derived from a reversible phase transition; said method comprising the steps of: i) determining a molar ratio of at least one tetragonal perovskite compound to at least one non-tetragonal perovskite compound which, when combined to form a solid solution, provides a ceramic material comprising a major portion of a tetragonal phase having an axial ratio c/a of greater than 1.005 to 1.04; and ii) determining a molar ratio of at least one additional non-tetragonal perovskite compound to the combination of perovskite compounds from step i) at the determined molar ratio which, when combined to form a solid solution, provides a ceramic material comprising a major portion of a pseudo-cubic phase having an axial ratio c/a of from 0.995 to 1.005 and/or a rhombohedral angle of 90±0.5 degrees.
METHODS OF IDENTIFYING A CERAMIC MATERIAL EXHIBITING AN ELECTRIC FIELD INDUCED STRAIN DERIVED FROM A REVERSIBLE PHASE TRANSITION, METHODS OF PREPARATION AND CERAMIC MATERIALS OBTAINABLE THEREFROM
VERFAHREN ZUR IDENTIFIZIERUNG EINES KERAMIKMATERIALS MIT ÜBER EIN ELEKTRISCHES FELD INDUZIERTER DEHNUNG AUS EINEM REVERSIBLEN PHASENÜBERGANG, VERFAHREN ZUR HERSTELLUNG UND DARAUS ERHÄLTLICHE KERAMIKMATERIALIEN
PROCÉDÉS D'IDENTIFICATION D'UN MATÉRIAU CÉRAMIQUE PRÉSENTANT UNE CONTRAINTE INDUITE PAR UN CHAMP ÉLECTRIQUE DÉRIVÉE D'UNE TRANSITION DE PHASE RÉVERSIBLE, PROCÉDÉS DE PRÉPARATION ET MATÉRIAUX CÉRAMIQUES POUVANT ÊTRE OBTENUS À PARTIR DE CEUX-CI
CANN DAVID (author) / GIBBONS BRADY (author) / MARDILOVICH PETER (author)
2019-12-11
Patent
Electronic Resource
English
European Patent Office | 2019
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