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METHOD FOR MANUFACTURING PROTON CONDUCTING OXIDE FUEL CELL
PROBLEM TO BE SOLVED: To provide a method for manufacturing a proton conducting oxide fuel cell, which enables the formation of a dense electrolyte layer without causing the decrease in electric property, such as the interface delamination of an electrolyte layer and a positive electrode or the increase in interface resistance, and which is advantageous for achievement of the increase in area and mass production.SOLUTION: A method for manufacturing a proton conducting oxide fuel cell comprises the steps of: synthesizing a sintering assistant represented by BaMOor BaY2MO(where M is Ni, Cu or Zn); preparing a negative electrode layer including a yttrium-doped barium cerate-zirconate (BCZY) and a nickel oxide (NiO) which is a transition metal oxide; dispersing the yttrium-doped barium cerate-zirconate (BCZY) in solvent to prepare an electrolyte paste; screen printing the electrolyte paste on the negative electrode layer to form an electrolyte layer; and sintering the negative electrode layer and the electrolyte layer concurrently.SELECTED DRAWING: Figure 1
【課題】電解質層と正極との界面剥離や界面抵抗の増加等の電気的物性の減少なしに緻密な電解質層を形成し、大面積化または量産化に有利なプロトン伝導性酸化物燃料電池の製造方法を提供する。【解決手段】BaMO2又はBaY2MO5(前記Mは、Ni、CuまたはZn)で表される焼結助剤を合成するステップ及びイットリウムがドープされたバリウムセレート−ジルコネート(BCZY)及び遷移金属酸化物であるニッケル酸化物(NiO)を含む負極層を準備するステップ、イットリウムがドープされたバリウムセレート−ジルコネート(BCZY)を溶媒中に分散させて電解質ペーストを準備し、前記電解質ペーストを前記負極層上にスクリーン印刷して電解質層を形成するステップ、及び前記負極層と電解質層とを同時焼結するステップを含むプロトン伝導性酸化物燃料電池の製造方法。【選択図】図1
METHOD FOR MANUFACTURING PROTON CONDUCTING OXIDE FUEL CELL
PROBLEM TO BE SOLVED: To provide a method for manufacturing a proton conducting oxide fuel cell, which enables the formation of a dense electrolyte layer without causing the decrease in electric property, such as the interface delamination of an electrolyte layer and a positive electrode or the increase in interface resistance, and which is advantageous for achievement of the increase in area and mass production.SOLUTION: A method for manufacturing a proton conducting oxide fuel cell comprises the steps of: synthesizing a sintering assistant represented by BaMOor BaY2MO(where M is Ni, Cu or Zn); preparing a negative electrode layer including a yttrium-doped barium cerate-zirconate (BCZY) and a nickel oxide (NiO) which is a transition metal oxide; dispersing the yttrium-doped barium cerate-zirconate (BCZY) in solvent to prepare an electrolyte paste; screen printing the electrolyte paste on the negative electrode layer to form an electrolyte layer; and sintering the negative electrode layer and the electrolyte layer concurrently.SELECTED DRAWING: Figure 1
【課題】電解質層と正極との界面剥離や界面抵抗の増加等の電気的物性の減少なしに緻密な電解質層を形成し、大面積化または量産化に有利なプロトン伝導性酸化物燃料電池の製造方法を提供する。【解決手段】BaMO2又はBaY2MO5(前記Mは、Ni、CuまたはZn)で表される焼結助剤を合成するステップ及びイットリウムがドープされたバリウムセレート−ジルコネート(BCZY)及び遷移金属酸化物であるニッケル酸化物(NiO)を含む負極層を準備するステップ、イットリウムがドープされたバリウムセレート−ジルコネート(BCZY)を溶媒中に分散させて電解質ペーストを準備し、前記電解質ペーストを前記負極層上にスクリーン印刷して電解質層を形成するステップ、及び前記負極層と電解質層とを同時焼結するステップを含むプロトン伝導性酸化物燃料電池の製造方法。【選択図】図1
METHOD FOR MANUFACTURING PROTON CONDUCTING OXIDE FUEL CELL
プロトン伝導性酸化物燃料電池の製造方法
LEE JONG HO (author) / AN HYEG SOON (author) / CHOI SUNG MIN (author) / YOON KYUNG JOONG (author) / SON JI-WON (author) / KIM BYUNG KOOK (author) / LEE HAE-WON (author) / PARK MANSOO (author) / KIM HYOUNGCHUL (author) / JI HO-IL (author)
2018-11-29
Patent
Electronic Resource
Japanese
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