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An electrochemical cell stack according to a second aspect of the present invention includes an electrochemical cell and a manifold supporting a base end of the electrochemical cell. The electrochemical cell includes an electric conductive support substrate and a power generation unit disposed on the support substrate. Additionally, a gas flow path is provided in the support substrate. The power generation unit includes an anode disposed on a first main surface of the support substrate, a cathode, and a solid electrolyte layer disposed between the anode and the cathode. Additionally, the solid electrolyte layer contains a zirconia-based material as a main component thereof. The solid electrolyte layer includes a base end portion positioned on a side of the base end and a separated portion positioned separated from the base end. The base end portion includes a first area covering within 3 μm from an anode side surface, and a second area provided on the first area. An intensity ratio of tetragonal zirconia to cubic zirconia in a Raman spectrum in the first area is greater than an intensity ratio of tetragonal zirconia to cubic zirconia in the Raman spectrum in the second area.
An electrochemical cell stack according to a second aspect of the present invention includes an electrochemical cell and a manifold supporting a base end of the electrochemical cell. The electrochemical cell includes an electric conductive support substrate and a power generation unit disposed on the support substrate. Additionally, a gas flow path is provided in the support substrate. The power generation unit includes an anode disposed on a first main surface of the support substrate, a cathode, and a solid electrolyte layer disposed between the anode and the cathode. Additionally, the solid electrolyte layer contains a zirconia-based material as a main component thereof. The solid electrolyte layer includes a base end portion positioned on a side of the base end and a separated portion positioned separated from the base end. The base end portion includes a first area covering within 3 μm from an anode side surface, and a second area provided on the first area. An intensity ratio of tetragonal zirconia to cubic zirconia in a Raman spectrum in the first area is greater than an intensity ratio of tetragonal zirconia to cubic zirconia in the Raman spectrum in the second area.
Electrochemical cell stack
OHMORI MAKOTO (author)
2020-11-24
Patent
Electronic Resource
English
IPC:
H01M
Verfahren oder Mittel, z.B. Batterien, für die direkte Umwandlung von chemischer in elektrische Energie
,
PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
/
B32B
LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
,
Schichtkörper, d.h. aus Ebenen oder gewölbten Schichten, z.B. mit zell- oder wabenförmiger Form, aufgebaute Erzeugnisse
/
C04B
Kalk
,
LIME