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Scandia-stabilized zirconia powder for solid oxide fuel cells, method for producing same, scandia-stabilized zirconia sintered body for solid oxide fuel cells, method for producing said scandia-stabilized zirconia sintered body for solid oxide fuel cells, and solid oxide fuel cell
The present invention provides a scandia-stabilized zirconia powder for solid oxide fuel cells or a scandia-stabilized zirconia sintered body for solid oxide fuel cells, each having high crystal structure stability, low grain-boundary resistivity, and high ionic conductivity; and the production methods of these. The scandia-stabilized zirconia powder for solid oxide fuel cells comprises a compound represented by formula (1): (ZrO2)1-x-a(Sc2O3)x(Al2O3)a. In formula (1), 0.09≤x≤0.11 and 0.002≤a<0.01 are satisfied. The scandia-stabilized zirconia powder has a rhombohedral phase crystal structure. The sintered body of the scandia-stabilized zirconia powder has a cubic phase crystal structure. The sintered body of the scandia-stabilized zirconia powder has a grain-boundary resistivity of 12 Ω·cm or less at 550° C.
Scandia-stabilized zirconia powder for solid oxide fuel cells, method for producing same, scandia-stabilized zirconia sintered body for solid oxide fuel cells, method for producing said scandia-stabilized zirconia sintered body for solid oxide fuel cells, and solid oxide fuel cell
The present invention provides a scandia-stabilized zirconia powder for solid oxide fuel cells or a scandia-stabilized zirconia sintered body for solid oxide fuel cells, each having high crystal structure stability, low grain-boundary resistivity, and high ionic conductivity; and the production methods of these. The scandia-stabilized zirconia powder for solid oxide fuel cells comprises a compound represented by formula (1): (ZrO2)1-x-a(Sc2O3)x(Al2O3)a. In formula (1), 0.09≤x≤0.11 and 0.002≤a<0.01 are satisfied. The scandia-stabilized zirconia powder has a rhombohedral phase crystal structure. The sintered body of the scandia-stabilized zirconia powder has a cubic phase crystal structure. The sintered body of the scandia-stabilized zirconia powder has a grain-boundary resistivity of 12 Ω·cm or less at 550° C.
Scandia-stabilized zirconia powder for solid oxide fuel cells, method for producing same, scandia-stabilized zirconia sintered body for solid oxide fuel cells, method for producing said scandia-stabilized zirconia sintered body for solid oxide fuel cells, and solid oxide fuel cell
TAMAZAKI FUMINORI (author)
2022-10-04
Patent
Electronic Resource
English
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