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REFRACTORY MATERIAL AND CASTING NOZZLE
Provided is a refractory material having both excellent erosion/corrosion resistance and thermal shock resistance, which has hardly been obtainable by conventional techniques, and a casting nozzle using the refractory material. The refractory material of the present invention contains: MgO in an amount of 40 mass % or more; a free carbon component in an amount of 4 to 30 mass %; and one or more selected from the group consisting of B2O3, P2O5, SiO2 and TiO2, in a total amount of 0.3 to 3 mass %, with the remainder being at least one other type of additional refractory component, wherein a void layer exists in an interface between a carbon-containing matrix microstructure residing at least on opposite sides of a maximum-size one of a plurality of MgO-containing particles in the refractory material, and the maximum-size MgO-containing particle, wherein a sum of respective thicknesses of the void layer at two positions on the opposite sides is 0.2 to 3.0% in terms of a ratio with respect to a particle size of the maximum-size MgO-containing particle, and wherein an inorganic compound comprised of MgO and the one or more selected from the group consisting of B2O3, P2O5, SiO2 and TiO2 exists in an entirety or a part of a surface of each of the plurality of MgO-containing particles.
REFRACTORY MATERIAL AND CASTING NOZZLE
Provided is a refractory material having both excellent erosion/corrosion resistance and thermal shock resistance, which has hardly been obtainable by conventional techniques, and a casting nozzle using the refractory material. The refractory material of the present invention contains: MgO in an amount of 40 mass % or more; a free carbon component in an amount of 4 to 30 mass %; and one or more selected from the group consisting of B2O3, P2O5, SiO2 and TiO2, in a total amount of 0.3 to 3 mass %, with the remainder being at least one other type of additional refractory component, wherein a void layer exists in an interface between a carbon-containing matrix microstructure residing at least on opposite sides of a maximum-size one of a plurality of MgO-containing particles in the refractory material, and the maximum-size MgO-containing particle, wherein a sum of respective thicknesses of the void layer at two positions on the opposite sides is 0.2 to 3.0% in terms of a ratio with respect to a particle size of the maximum-size MgO-containing particle, and wherein an inorganic compound comprised of MgO and the one or more selected from the group consisting of B2O3, P2O5, SiO2 and TiO2 exists in an entirety or a part of a surface of each of the plurality of MgO-containing particles.
REFRACTORY MATERIAL AND CASTING NOZZLE
MORIKAWA KATSUMI (author) / SASAKI AKINARI (author) / MAKINO TARO (author) / LI LING (author)
2016-10-13
Patent
Electronic Resource
English