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Ion conducting polymer comprising partially branched block copolymer and use thereof
The present invention relates to an ion conducting polymer including a partially branched block copolymer; a method of preparing the same; an ion conductor including the ion conducting polymer; an electrolytic membrane including the ion conducting polymer; a membrane-electrode assembly comprising the electrolytic membrane, and a battery comprising the same; and a separation membrane for a redox flow battery including the ion conducting polymer, and a redox flow battery comprising same. Specifically, the partially branched block copolymer includes: a first block including a hydrophilic first polymer; a second block derived from a hydrophobic second polymer having two or more reactive groups respectively on its both ends, in such a way as to form branching points forming side branches on a main chain; and optionally a third block including a hydrophobic third polymer. The ion conducting polymer in the form of a partially branched block copolymer can prepare a polymer membrane having improved conductivity and superior physical properties such as tensile strength elongation at break, etc., while having the same or similar ion-exchange capacity (IEC), percentage water absorption and/or degree of dimensional change compared to conventional ion conducting polymers in the form of linear block copolymers. Because of such outstanding physical properties, the polymer membrane can be used as a membrane-electrode assembly for a fuel cell, and a redox flow battery comprising the same as a separation membrane can exhibit outstanding cell performance and maintain high discharge charge capacity retention rate even when repeatedly charged and discharged several times.
Ion conducting polymer comprising partially branched block copolymer and use thereof
The present invention relates to an ion conducting polymer including a partially branched block copolymer; a method of preparing the same; an ion conductor including the ion conducting polymer; an electrolytic membrane including the ion conducting polymer; a membrane-electrode assembly comprising the electrolytic membrane, and a battery comprising the same; and a separation membrane for a redox flow battery including the ion conducting polymer, and a redox flow battery comprising same. Specifically, the partially branched block copolymer includes: a first block including a hydrophilic first polymer; a second block derived from a hydrophobic second polymer having two or more reactive groups respectively on its both ends, in such a way as to form branching points forming side branches on a main chain; and optionally a third block including a hydrophobic third polymer. The ion conducting polymer in the form of a partially branched block copolymer can prepare a polymer membrane having improved conductivity and superior physical properties such as tensile strength elongation at break, etc., while having the same or similar ion-exchange capacity (IEC), percentage water absorption and/or degree of dimensional change compared to conventional ion conducting polymers in the form of linear block copolymers. Because of such outstanding physical properties, the polymer membrane can be used as a membrane-electrode assembly for a fuel cell, and a redox flow battery comprising the same as a separation membrane can exhibit outstanding cell performance and maintain high discharge charge capacity retention rate even when repeatedly charged and discharged several times.
Ion conducting polymer comprising partially branched block copolymer and use thereof
HONG YOUNG TAIK (author) / LEE JANG YONG (author) / KIM TAE HO (author) / YU DUK MAN (author) / KIM SEOG JE (author)
2018-05-22
Patent
Electronic Resource
English
IPC:
C08F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
,
Makromolekulare Verbindungen, erhalten durch Reaktionen, an denen nur ungesättigte Kohlenstoff-Kohlenstoff-Bindungen beteiligt sind
/
C08G
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
,
Makromolekulare Verbindungen, anders erhalten als durch Reaktionen, an denen nur ungesättigte Kohlenstoff-Kohlenstoff-Bindungen beteiligt sind
/
E01C
Bau von Straßen, Sportplätzen oder dgl., Decken dafür
,
CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE
/
H01M
Verfahren oder Mittel, z.B. Batterien, für die direkte Umwandlung von chemischer in elektrische Energie
,
PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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