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Blended Calcium Aluminate-Calcium Sulfate Cement-Based Grout for P-Reactor Vessel In-Situ Decommissioning
The objective of this report is to document laboratory testing of blended calcium aluminate - calcium hemihydrate grouts for P-Reactor vessel in-situ decommissioning. Blended calcium aluminate - calcium hemihydrate cement-based grout was identified as candidate material for filling (physically stabilizing) the 105-P Reactor vessel (RV) because it is less alkaline than portland cement-based grout which has a pH greater than 12.4. In addition, blended calcium aluminate - calcium hemihydrate cement compositions can be formulated such that the primary cementitious phase is a stable crystalline material. A less alkaline material (pH < or = 10.5) was desired to address a potential materials compatibility issue caused by corrosion of aluminum metal in highly alkaline environments such as that encountered in portland cement grouts (Wiersma, 2009a and b, Wiersma, 2010, and Serrato and Langton, 2010). Information concerning access points into the P-Reactor vessel and amount of aluminum metal in the vessel is provided elsewhere (Griffin, 2010, Stefanko, 2009 and Wiersma, 2009 and 2010, Bobbitt, 2010, respectively). Radiolysis calculations are also provided in a separate document (Reyes-Jimenez, 2010).
Blended Calcium Aluminate-Calcium Sulfate Cement-Based Grout for P-Reactor Vessel In-Situ Decommissioning
The objective of this report is to document laboratory testing of blended calcium aluminate - calcium hemihydrate grouts for P-Reactor vessel in-situ decommissioning. Blended calcium aluminate - calcium hemihydrate cement-based grout was identified as candidate material for filling (physically stabilizing) the 105-P Reactor vessel (RV) because it is less alkaline than portland cement-based grout which has a pH greater than 12.4. In addition, blended calcium aluminate - calcium hemihydrate cement compositions can be formulated such that the primary cementitious phase is a stable crystalline material. A less alkaline material (pH < or = 10.5) was desired to address a potential materials compatibility issue caused by corrosion of aluminum metal in highly alkaline environments such as that encountered in portland cement grouts (Wiersma, 2009a and b, Wiersma, 2010, and Serrato and Langton, 2010). Information concerning access points into the P-Reactor vessel and amount of aluminum metal in the vessel is provided elsewhere (Griffin, 2010, Stefanko, 2009 and Wiersma, 2009 and 2010, Bobbitt, 2010, respectively). Radiolysis calculations are also provided in a separate document (Reyes-Jimenez, 2010).
Blended Calcium Aluminate-Calcium Sulfate Cement-Based Grout for P-Reactor Vessel In-Situ Decommissioning
D. B. Stefanko (author) / C. A. Langton (author)
2011
49 pages
Report
No indication
English
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