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Solid olive waste in environmental cleanup: Enhanced nitrite ion removal by ZnCl^sub 2^-activated carbon
This communication describes how olive solid wastes can be used to prepare activated carbon (AC), with soundly high surface areas, suitable to remove nitrite ions from water. Solid olive wastes, so called Jeft, separated as unwanted bi-products from olive oil mills, have been converted into charcoal. The charcoal was then physically and/or chemically activated using different compounds namely conc. H...PO... or ZnCl... Charcoal carbonization was performed under inert atmosphere to avoid loss of heated carbon by oxidation with air. Surface area measurements and SEM micrographs showed that activation using ZnCl... yields AC with highest surface area and more porous surfaces. The ZnCl...-activated carbon was then used to remove nitrite ions from water by adsorption. Effects of different parameters on value of surface area and adsorption capacity of the AC were investigated. Commercial AC materials were used as reference for comparison. The AC showed higher adsorption capacity toward nitrite than other reported adsorbents. The results suggest that using 5 g of the ZnCl...-activated carbon per liter of heavily nitrite-contaminated water (50 ppm) may bring the contaminant concentration down to the WHO accepted concentration limits within 60 min. This work highlights the future feasibility of using olive waste as feed stocks to produce useful renewable materials while keeping in mind the wisdom "make wastes work in environmental protection". (ProQuest: ... denotes formulae/symbols omitted.)
Solid olive waste in environmental cleanup: Enhanced nitrite ion removal by ZnCl^sub 2^-activated carbon
This communication describes how olive solid wastes can be used to prepare activated carbon (AC), with soundly high surface areas, suitable to remove nitrite ions from water. Solid olive wastes, so called Jeft, separated as unwanted bi-products from olive oil mills, have been converted into charcoal. The charcoal was then physically and/or chemically activated using different compounds namely conc. H...PO... or ZnCl... Charcoal carbonization was performed under inert atmosphere to avoid loss of heated carbon by oxidation with air. Surface area measurements and SEM micrographs showed that activation using ZnCl... yields AC with highest surface area and more porous surfaces. The ZnCl...-activated carbon was then used to remove nitrite ions from water by adsorption. Effects of different parameters on value of surface area and adsorption capacity of the AC were investigated. Commercial AC materials were used as reference for comparison. The AC showed higher adsorption capacity toward nitrite than other reported adsorbents. The results suggest that using 5 g of the ZnCl...-activated carbon per liter of heavily nitrite-contaminated water (50 ppm) may bring the contaminant concentration down to the WHO accepted concentration limits within 60 min. This work highlights the future feasibility of using olive waste as feed stocks to produce useful renewable materials while keeping in mind the wisdom "make wastes work in environmental protection". (ProQuest: ... denotes formulae/symbols omitted.)
Solid olive waste in environmental cleanup: Enhanced nitrite ion removal by ZnCl^sub 2^-activated carbon
Ahed Zyoud (author) / Hiba NI Nassar / Amer El-Hamouz / Hikmat S Hilal
2015
Article (Journal)
English
BKL:
43.00
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