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Nickel–molybdenum sulfide naphthalene hydrogenation catalysts synthesized by the in situ decomposition of oil-soluble precursors

Sizova, I. A. / Maksimov, A. L.

Abstract Nickel–molybdenum sulfide catalysts for the hydrogenation of aromatic hydrocarbons have been prepared by the in situ decomposition of oil-soluble precursors Mo(CO)6 and Ni(С7H15СOO)2 in a hydrocarbon feedstock and characterized by HRTEM and XPS. The resulting Ni–Mo sulfide material exhibits high catalytic activity in the naphthalene hydrogenation reaction. An optimum Mo/Ni ratio of 1/2 has been selected.

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Nickel–molybdenum sulfide naphthalene hydrogenation catalysts synthesized by the in situ decomposition of oil-soluble precursors

Sizova, I. A. / Maksimov, A. L.

Abstract Nickel–molybdenum sulfide catalysts for the hydrogenation of aromatic hydrocarbons have been prepared by the in situ decomposition of oil-soluble precursors Mo(CO)6 and Ni(С7H15СOO)2 in a hydrocarbon feedstock and characterized by HRTEM and XPS. The resulting Ni–Mo sulfide material exhibits high catalytic activity in the naphthalene hydrogenation reaction. An optimum Mo/Ni ratio of 1/2 has been selected.

Nickel–molybdenum sulfide naphthalene hydrogenation catalysts synthesized by the in situ decomposition of oil-soluble precursors

Sizova, I. A. / Maksimov, A. L.

Abstract Nickel–molybdenum sulfide catalysts for the hydrogenation of aromatic hydrocarbons have been prepared by the in situ decomposition of oil-soluble precursors Mo(CO)6 and Ni(С7H15СOO)2 in a hydrocarbon feedstock and characterized by HRTEM and XPS. The resulting Ni–Mo sulfide material exhibits high catalytic activity in the naphthalene hydrogenation reaction. An optimum Mo/Ni ratio of 1/2 has been selected.

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Title:

Nickel–molybdenum sulfide naphthalene hydrogenation catalysts synthesized by the in situ decomposition of oil-soluble precursors

Contributors:

Sizova, I. A. (author) / Maksimov, A. L. (author)

Published in:

Petroleum Chemistry ; 57 ; 595-599

Publication date:

2017-07-01

Size:

5 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S096554411707009X

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

molybdenum hexacarbonyl , unsupported catalysts , nickel–molybdenum sulfide catalyst , hydrogenation of aromatic hydrocarbons Chemistry , Industrial Chemistry/Chemical Engineering

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