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Bridged Mixed Valence Phthalocyaninato-Metal Compounds

Hirsch, A. / Hanack, M.

Abstract Bridged mixed valence phthalocyaninato-metal dimers, trimers and polymers (M = Fe, Co) with the central metal in the oxidation state of +II and +III and cyanide and pyrazine as bridging ligands have been synthesized. The synthesis has been carried out at either by coupling of PcM(L)CN (M = Fe(III), Co(III); L = pyz, py, t-bupy) with PcFe(NH3)2 and substituting the weak coordinated ammonia or by thermal decomposition of PcFe(pyz)CN. The infrared, Mößbauer and electrical properties of these compounds have been investigated.

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Bridged Mixed Valence Phthalocyaninato-Metal Compounds

Hirsch, A. / Hanack, M.

Abstract Bridged mixed valence phthalocyaninato-metal dimers, trimers and polymers (M = Fe, Co) with the central metal in the oxidation state of +II and +III and cyanide and pyrazine as bridging ligands have been synthesized. The synthesis has been carried out at either by coupling of PcM(L)CN (M = Fe(III), Co(III); L = pyz, py, t-bupy) with PcFe(NH3)2 and substituting the weak coordinated ammonia or by thermal decomposition of PcFe(pyz)CN. The infrared, Mößbauer and electrical properties of these compounds have been investigated.

Bridged Mixed Valence Phthalocyaninato-Metal Compounds

Hirsch, A. / Hanack, M.

Abstract Bridged mixed valence phthalocyaninato-metal dimers, trimers and polymers (M = Fe, Co) with the central metal in the oxidation state of +II and +III and cyanide and pyrazine as bridging ligands have been synthesized. The synthesis has been carried out at either by coupling of PcM(L)CN (M = Fe(III), Co(III); L = pyz, py, t-bupy) with PcFe(NH3)2 and substituting the weak coordinated ammonia or by thermal decomposition of PcFe(pyz)CN. The infrared, Mößbauer and electrical properties of these compounds have been investigated.

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Title:

Bridged Mixed Valence Phthalocyaninato-Metal Compounds

Contributors:

Hirsch, A. (author) / Hanack, M. (author)

Published in:

Conjugated Polymeric Materials: Opportunities in Electronics, Optoelectronics, and Molecular Electronics ; 163-169

NATO ASI Series ; 182

Publication date:

1990-01-01

Size:

7 pages

ISBN:

978-94-010-7416-2 , 978-94-009-2041-5

ISSN:

DOI:

https://doi.org/10.1007/978-94-009-2041-5_12

Type of media:

Article/Chapter (Book)

Type of material:

Electronic Resource

Language:

English

Keywords:

Central Metal , Isomer Shift , Mixed Valence , Quadrupole Doublet , Mixed Valence Compound Chemistry , Industrial Chemistry/Chemical Engineering , Characterization and Evaluation of Materials , Organic Chemistry , Optics, Lasers, Photonics, Optical Devices

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