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Alkylation of Aromatic Compounds in the Presence of Catalysts Based on Mesoporous Phenol–Formaldehyde Polymers

Boronoev, M. P. / Gotszyun, Ma / Talanova, M. Yu. / Karakhanov, E. A.

Abstract A catalyst based on a mesoporous phenol–formaldehyde polymer (MPF) as an organic support modified with the IMHSO4 ionic liquid has been synthesized. The catalytic activity of the sample has been studied in the alkylation of aromatic compounds with octene-1. It has been found that the use of the catalyst in phenol alkylation leads to the formation of both alkylphenols (C-alkylates) and alkyl phenyl ethers (O-alkylates) with a total yield of up to 60%. In the case of alkylation of benzene and benzene derivatives, significant conversion values (45–50%) are achieved only for toluene and anisole.

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Alkylation of Aromatic Compounds in the Presence of Catalysts Based on Mesoporous Phenol–Formaldehyde Polymers

Boronoev, M. P. / Gotszyun, Ma / Talanova, M. Yu. / Karakhanov, E. A.

Abstract A catalyst based on a mesoporous phenol–formaldehyde polymer (MPF) as an organic support modified with the IMHSO4 ionic liquid has been synthesized. The catalytic activity of the sample has been studied in the alkylation of aromatic compounds with octene-1. It has been found that the use of the catalyst in phenol alkylation leads to the formation of both alkylphenols (C-alkylates) and alkyl phenyl ethers (O-alkylates) with a total yield of up to 60%. In the case of alkylation of benzene and benzene derivatives, significant conversion values (45–50%) are achieved only for toluene and anisole.

Alkylation of Aromatic Compounds in the Presence of Catalysts Based on Mesoporous Phenol–Formaldehyde Polymers

Boronoev, M. P. / Gotszyun, Ma / Talanova, M. Yu. / Karakhanov, E. A.

Abstract A catalyst based on a mesoporous phenol–formaldehyde polymer (MPF) as an organic support modified with the IMHSO4 ionic liquid has been synthesized. The catalytic activity of the sample has been studied in the alkylation of aromatic compounds with octene-1. It has been found that the use of the catalyst in phenol alkylation leads to the formation of both alkylphenols (C-alkylates) and alkyl phenyl ethers (O-alkylates) with a total yield of up to 60%. In the case of alkylation of benzene and benzene derivatives, significant conversion values (45–50%) are achieved only for toluene and anisole.

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Title:

Alkylation of Aromatic Compounds in the Presence of Catalysts Based on Mesoporous Phenol–Formaldehyde Polymers

Contributors:

Boronoev, M. P. (author) / Gotszyun, Ma (author) / Talanova, M. Yu. (author) / Karakhanov, E. A. (author)

Published in:

Petroleum Chemistry ; 58 ; 412-417

Publication date:

2018-05-01

Size:

6 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544118050043

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

mesoporous phenol–formaldehyde polymers , alkylation , imidazole ionic liquids Chemistry , Industrial Chemistry/Chemical Engineering

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