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Decomposition of cumene hydroperoxide over molybdenum oxo-peroxo compounds
Abstract The features of the catalytic decomposition of cumene hydroperoxide (CHP) were studied by the pulse technique in an inert gas atmosphere over the temperature range 90–120°C and the concentration range 0.1–2.5 mol/l. As a catalyst, molybdenum(VI) oxo-peroxo compounds active in the olefin oxidation reaction were used, which were prepared from cumene hydroperoxide and hydrogen peroxide. The rate and activation parameters for the formation and degradation of the CHP-catalyst complex were determined, as well as the thermodynamic characteristics of complexation.
Decomposition of cumene hydroperoxide over molybdenum oxo-peroxo compounds
Abstract The features of the catalytic decomposition of cumene hydroperoxide (CHP) were studied by the pulse technique in an inert gas atmosphere over the temperature range 90–120°C and the concentration range 0.1–2.5 mol/l. As a catalyst, molybdenum(VI) oxo-peroxo compounds active in the olefin oxidation reaction were used, which were prepared from cumene hydroperoxide and hydrogen peroxide. The rate and activation parameters for the formation and degradation of the CHP-catalyst complex were determined, as well as the thermodynamic characteristics of complexation.
Decomposition of cumene hydroperoxide over molybdenum oxo-peroxo compounds
Yelimanova, G. G. (author) / Suvorova, I. A. (author) / Batyrshin, N. N. (author) / Kharlampidi, Kh. E. (author)
Petroleum Chemistry ; 49 ; 327-330
2009-07-01
4 pages
Article (Journal)
Electronic Resource
English
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