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Hydrogenation of aromatic nitro compounds on palladium-containing anion-exchange resins

Abdullaev, M. G. / Gebekova, Z. G.

Abstract Hydrogenation of aromatic nitro compounds to the corresponding amines on palladium-containing anion-exchange resins has been studied under mild conditions. It has been found that stericity has a significant effect on the activity and selectivity of the hydrogenation reaction. High efficiency of the palladium-containing anion-exchange resins in the synthesis of aromatic amines has been demonstrated. Halonitrobenzenes undergo intense dehalogenation resulting in a low yield of the corresponding amine.

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Hydrogenation of aromatic nitro compounds on palladium-containing anion-exchange resins

Abdullaev, M. G. / Gebekova, Z. G.

Abstract Hydrogenation of aromatic nitro compounds to the corresponding amines on palladium-containing anion-exchange resins has been studied under mild conditions. It has been found that stericity has a significant effect on the activity and selectivity of the hydrogenation reaction. High efficiency of the palladium-containing anion-exchange resins in the synthesis of aromatic amines has been demonstrated. Halonitrobenzenes undergo intense dehalogenation resulting in a low yield of the corresponding amine.

Hydrogenation of aromatic nitro compounds on palladium-containing anion-exchange resins

Abdullaev, M. G. / Gebekova, Z. G.

Abstract Hydrogenation of aromatic nitro compounds to the corresponding amines on palladium-containing anion-exchange resins has been studied under mild conditions. It has been found that stericity has a significant effect on the activity and selectivity of the hydrogenation reaction. High efficiency of the palladium-containing anion-exchange resins in the synthesis of aromatic amines has been demonstrated. Halonitrobenzenes undergo intense dehalogenation resulting in a low yield of the corresponding amine.

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Title:

Hydrogenation of aromatic nitro compounds on palladium-containing anion-exchange resins

Contributors:

Abdullaev, M. G. (author) / Gebekova, Z. G. (author)

Published in:

Petroleum Chemistry ; 56 ; 146-150

Publication date:

2016-02-01

Size:

5 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S096554411602002X

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

synthesis , hydrogenation , aromatic amines , palladium-containing anion-exchange resins Chemistry , Industrial Chemistry/Chemical Engineering

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