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Catalytic oxidation of alkylbenzenes with ozone in acetic acid in the presence of strong acids

Potapenko, E. V. / Andreev, P. Yu.

Abstract The oxidation of ethylbenzene with ozone in the acetic acid-sulfuric acid system in the presence of Mn(II) acetate and cumene in the acetic acid-trifluoroacetic acid system in the presence of Co(II) acetate has been studied. The main factors that affect the catalytic ozonation of alkylbenzenes are discussed. A redox catalysis mechanism is proposed. The kinetic characteristics of the main stages of the catalytic cycle have been determined.

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Catalytic oxidation of alkylbenzenes with ozone in acetic acid in the presence of strong acids

Potapenko, E. V. / Andreev, P. Yu.

Abstract The oxidation of ethylbenzene with ozone in the acetic acid-sulfuric acid system in the presence of Mn(II) acetate and cumene in the acetic acid-trifluoroacetic acid system in the presence of Co(II) acetate has been studied. The main factors that affect the catalytic ozonation of alkylbenzenes are discussed. A redox catalysis mechanism is proposed. The kinetic characteristics of the main stages of the catalytic cycle have been determined.

Catalytic oxidation of alkylbenzenes with ozone in acetic acid in the presence of strong acids

Potapenko, E. V. / Andreev, P. Yu.

Abstract The oxidation of ethylbenzene with ozone in the acetic acid-sulfuric acid system in the presence of Mn(II) acetate and cumene in the acetic acid-trifluoroacetic acid system in the presence of Co(II) acetate has been studied. The main factors that affect the catalytic ozonation of alkylbenzenes are discussed. A redox catalysis mechanism is proposed. The kinetic characteristics of the main stages of the catalytic cycle have been determined.

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Title:

Catalytic oxidation of alkylbenzenes with ozone in acetic acid in the presence of strong acids

Contributors:

Potapenko, E. V. (author) / Andreev, P. Yu. (author)

Published in:

Petroleum Chemistry ; 52 ; 113-118

Publication date:

2012-03-01

Size:

6 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544112020120

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Ozone , Cumene , Petroleum Chemistry , Alkylbenzenes , Ethylbenzene Chemistry , Industrial Chemistry/Chemical Engineering

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